82299-64-7Relevant academic research and scientific papers
ACYCLIC STEREOSELECTION. ERYTHROSELECTIVE ALDOL CONDENSATION OF 4-ACYL-2,3-DIHYDRO-4H-1,4-BENZOTHIAZINE AND 10-ACYLPHENOTHIAZINE.
Babudri, F.,Di Nunno, L.,Florio, S.
, p. 3883 - 3886 (2007/10/02)
The title amides undergo aldol-type cross-condensation providing aldols of exclusive erythro configuration.The preferred cis geometry of the precursor amide enolate is likely to be at origin of the erythro selection.
Facile Deacylation of N-Acyl-2,3-dihydrobenzo-1,4-thiazine 1-Oxide and 1,1 Dioxide
Florio, Saverio,Leng, John L.,Stirling, Charles J. M.
, p. 857 - 859 (2007/10/02)
The title amides react easily with methanolic sodium methoxide at room temperature affording 2,3-dihydrobenzo-1,4-thiazine 1-oxide and 1,1-dioxide and methylacetate.An unusual mechanism of deacylation is proposed.
