82364-94-1Relevant articles and documents
Chemistry of the vanadium-carbon σ bond. 2. Oxovanadium(IV) and oxovanadium(V) containing metal-to-carbon σ bonds
Vivanco, Marilin,Ruiz, Javier,Floriani, Carlo,Chiesi-Villa, Angiola,Rizzoli, Corrado
, p. 1802 - 1810 (2008/10/08)
This is a report on the oxidation of organometallic vanadium(III) homoleptic compounds to the corresponding oxovanadium( V) derivatives by the use of either epoxides or molecular oxygen. Complex 1, [V(Mes)3(THF)], gave a clean deoxygenation of