823782-85-0

Basic information

• Product Name: [(Pt(CH2Ph)(κ2-P,N-(oxazolinylmethyl)diphenylphosphine))2(μ-Cl)]BF4
• CAS NO: 823782-85-0
• Molecular Weight: 1233.25
• Mol File: 823782-85-0.mol

Chemical Properties

• CAS DataBase Reference: [(Pt(CH2Ph)(κ2-P,N-(oxazolinylmethyl)diphenylphosphine))2(μ-Cl)]BF4(CAS DataBase Reference)
• NIST Chemistry Reference: [(Pt(CH2Ph)(κ2-P,N-(oxazolinylmethyl)diphenylphosphine))2(μ-Cl)]BF4(823782-85-0)
• EPA Substance Registry System: [(Pt(CH2Ph)(κ2-P,N-(oxazolinylmethyl)diphenylphosphine))2(μ-Cl)]BF4(823782-85-0)

Safety Data

• Hazardous Substances Data: 823782-85-0(Hazardous Substances Data)

Upstream product

• 275377-93-0 2-[(diphenylphosphanyl)-methyl]-4,5-dihydrooxazole 
• 14104-20-2 silver tetrafluoroborate 
• 14243-64-2 (triphenylphosphine)gold(I) chloride 
• 823782-78-1 [Pt(CH2Ph)Cl(κ2-P,N-(oxazolinylmethyl)diphenylphosphine)] 

Relevant articles and documents

Electrophilic activation: Unexpected metal-metal bond-assisted Tl + chelation by a Pt-benzyl moiety instead of chloride abstraction

The major effect of replacing Ag(I) with Tl(I) salts, which are indiscriminately used as halide abstractors was investigated. It was found that in the absence of donor ligands such as, OTfs-s or acetonitrile, abstraction of the halide from Pt(II) complex or AgBF4 or AgPF 6 in CH2Cl2 resulted in formation of a dynamic cationic complex. The bonding interactions between the d8 Pt(II) and s2 Tl(I) center was assisted by π-donation from the benzyl ligand to the Tl+ ion.