275377-93-0

Basic information

• Product Name: Oxazole, 2-[(diphenylphosphino)methyl]-4,5-dihydro-
• CAS NO: 275377-93-0
• Molecular Formula: C16H16NOP
• Molecular Weight: 269.283
• Mol File: 275377-93-0.mol

Chemical Properties

• CAS DataBase Reference: Oxazole, 2-[(diphenylphosphino)methyl]-4,5-dihydro-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxazole, 2-[(diphenylphosphino)methyl]-4,5-dihydro-(275377-93-0)
• EPA Substance Registry System: Oxazole, 2-[(diphenylphosphino)methyl]-4,5-dihydro-(275377-93-0)

Safety Data

• Hazardous Substances Data: 275377-93-0(Hazardous Substances Data)

Upstream product

• 1120-64-5 2-methyl-4,5-dihydro-1,3-oxazole 
• 75-77-4 chloro-trimethyl-silane 
• 1079-66-9 chloro-diphenylphosphine 
• 23012-10-4 2-methyl-2-oxazoline 

Downstream Products

• 303181-30-8 trans,trans,trans-[RuCl₂((2-oxazolin-2-ylmethyl)diphenylphosphine)2] 
• 302357-74-0 [Mo(η-C5Me5)Cl3(2-(diphenylphosphinomethyl)oxazoline-κ2-P,N)]Cl 
• 275824-78-7 [CH₃PdCl(P(C₆H₅)2CH₂C₃H₄NO)] 
• 823782-90-7 [PtClPh(κ2-P,N-(oxazolinylmethyl)diphenylphosphine)] 
• 823782-78-1 [Pt(CH2Ph)Cl(κ2-P,N-(oxazolinylmethyl)diphenylphosphine)] 
• 954372-61-3 NiCl₂(2-diphenylphosphinomethyl-2-oxazoline) 
• 1073131-12-0 [PtI(Me)(2-diphenylphosphinomethyl-2-oxazoline)] 
• 1073131-14-2 [Pt(Me)2(2-diphenylphosphinomethyl-2-oxazoline)] 
• 1073131-13-1 [PtCl(Me)(2-diphenylphosphinomethyl-2-oxazoline)] 
• 1141247-16-6 [(C₃H₄NO)CH₂P(C₆H₅)2(CH₃)ZnCl₃] 
• 1337540-36-9 2-[(diphenylphosphinoyl)methyl]-4,5-dihydrooxazole 
• 823782-85-0 [(Pt(CH2Ph)(κ2-P,N-(oxazolinylmethyl)diphenylphosphine))2(μ-Cl)]BF4 
• 823782-81-6 [Pt(CH2Ph)(NCMe)(κ2-P,N-(oxazolinylmethyl)diphenylphosphine)]BF4 
• 823782-91-8 [Pt(C(O)Ph)Cl(κ2-P,N-(oxazolinylmethyl)diphenylphosphine)] 

Relevant articles and documents

Synthesis and lanthanide coordination chemistry of 2-[(phosphinoyl)methyl- 4,5-dihydrooxazole and 2-[(phosphinoyl)methylbenzoxazole ligands

Syntheses for [(diphenylphosphinoyl)methyl-4,5-dihydrooxazole (2) and [(diarylphosphinoyl)methylbenzoxazoles [aryl = phenyl (3), tolyl (4), 2-trifluoromethylphenyl (5) and 3,5-bis(trifluoromethyl)phenyl (6) have been developed. Each ligand has been charac

Structurally characterized intermediates in the stepwise insertion of CO-ethylene or CO-methyl acrylate into the metal-carbon bond of Pd(II) complexes stabilized by (phosphinomethyl)oxazoline ligands

The initial CO-ethylene or CO-methyl acrylate insertion steps into the Pd-Me bond of methylpalladium(ii) complexes with (phosphinomethyl)oxazoline ligands, leading to metallacycles, have been fully characterized, including by X-ray diffraction. The Royal

Synthesis and structure of Pd(n) complexes containing chelating (phosphinomethyl)oxazoline P,N-type ligands; copolymerisation of ethylene/CO

The ligands (2-oxazoIine-2-yImethyl)diphenylphosphine (III or PCH2ox) and (2-oxazoline-2-ylmethyl-4,4-dimethyl)diphenylphosphine (IV or PCH2oxMe2) have been used as chelates towards Pd(n) methyl complexes. The complexes [PdMe(Ci)(PCH2ox)] 2a and [PdMe(Cl)(PCH2oxMe2)] 2b were obtained from [PdMe(Cl)(cod)] (cod = cycloocta-l,5-diene) in 83% and 94% yield, respectively, and compared to [PdCI2(PCH2oxMe2)] 1 which was characterised by X-ray diffraction. A series of cationic methyl complexes obtained by chloride abstraction in the presence of MeCN, SMe2, P(OPh)3 or no added donor except the counter ion were prepared in order to evaluate their catalytic performances in ethylene/CO copolymerisation. The Royal Society of Chemistry 2000.