82423-73-2

Basic information

• Product Name: 1-chloro-1-phenylthiopentane
• Synonyms: 1-chloro-1-phenylthiopentane
• CAS NO: 82423-73-2
• Molecular Weight: 214.759
• Mol File: 82423-73-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-chloro-1-phenylthiopentane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-1-phenylthiopentane(82423-73-2)
• EPA Substance Registry System: 1-chloro-1-phenylthiopentane(82423-73-2)

Safety Data

• Hazardous Substances Data: 82423-73-2(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 628-17-1 amyl iodide 
• 1129-70-0 pentyl phenyl sulfide 

Downstream Products

• 25564-22-1 2-pentyl-2-cyclopenten-1-one 
• 2570-03-8 (+/-)-methyl trans-dihydrojasmonate 
• 2570-03-8 (+/-)-methyl dihydroepijasmonate 
• 80934-78-7 2-(1-Phenylthiopentyl)-cyclopentanone 
• 36638-50-3 α-(phenylthio)-pentyl cyanide 
• 82423-74-3 3-methoxycarbonylmethyl-2-(1-phenylthiopentyl)cyclopentanone 

Relevant articles and documents

Keten Silyl Acetal Chemistry; Simple Synthesis of Methyl Jasmonate and Related Compounds by Utilising Keten Methyl Dimethyl-t-butylsilyl Acetal

Conjugate addition of keten silyl acetals to α,β-unsaturated carbonyl compounds in acetonitrile gave a quantitative yield of the corresponding methyl (3-trialkylsiloxyalk-2-enyl)acetates; subsequent site-specific electrophilic substitution yielded the corresponding 2-substituted 3-(alkoxycarbonylmethyl)alkanones.These novel addition and sequential alkylation reactions could be applied to a simple synthesis of methyl jasmonate, methyl didehydrojasmonate, and methyl dihydrojasmonate.