82483-64-5Relevant academic research and scientific papers
A NEW METHOD OF ACYLATION AT β-POSITION OF ALIPHATIC AMINES
Shono, Tatsuya,Matsumura, Yoshihiro,Tsubata, Kenji,Sugihara, Yoshihiro
, p. 1201 - 1204 (2007/10/02)
A new method to introduce an acyl or a formyl group to β-position of aliphatic amines was studied using encarbamates, prepared from α-methoxycarbamates, as key intermediates.
Electroorganic Chemistry. 60. Electroorganic Synthesis of Enamides and Enecarbamates and Their Utilization in Organic Synthesis.
Shono, Tatsuya,Matsumura, Yoshihiro,Tsubata, Kenji,Sugihara, Yoshihiro,Yamane, Shin-ichiro,et. al.
, p. 6697 - 6703 (2007/10/02)
A variety of enecarbamates and enamides were synthesized from α-methoxy carbamates and α-methoxy amides prepared by anodic methoxylation of amine derivatives.Some new carbon-carbon bond-forming reactions and hydroxylation at the β position of amines have been accomplished by using these enecarbamates and enamides as key intermediates.Also, new synthetic routes of nicotinaldehyde and pyrrole derivatives have been exploited by utilizing anodic dimethoxylation of carbamates of piperidine and pyrrolidine, respectively.
