824952-30-9

Upstream product

• 108031-80-7 (2S,2'S-(2α,2'α,3aα,3a'α,4β,4'β,7β,7'β,7aα,7a'α))-2,2'-oxybis[octahydro-7,8,8-trimethyl-4,7-methanobenzofuran] 
• 579-43-1 (1S,2R)-1,2-diphenylethane-1,2-diol 
• 824952-29-6 [2S-(2α(1R*,2S*),3aα,4β,7β,7aα)]-2-[(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy]-1,2-diphenylethanol 
• 100-39-0 benzyl bromide 

Downstream Products

• 866457-07-0 oxophenylacetic acid (1R,2S)-2-benzyloxy-1,2-diphenylethyl ester 
• 118298-93-4 (+)-erythro-α,β-diphenyl-β-hydroxyethanol benzyl ether 

Relevant academic research and scientific papers

Synthesis of novel chiral hydrobenzoin mono-tert-butyl ethers derived from m-hydrobenzoin and their application as chiral auxiliaries in the diastereoselective reduction of α-keto esters

Three m-hydrobenzoin derived chiral hydrobenzoin mono-tert-butyl ethers were synthesized by a new reaction pathway and tested as chiral auxiliaries in the L-selectride mediated stereoselective reduction of their corresponding phenyl glyoxylates. As a result, improved stereoselectivities of up to a ratio of 92:8 compared to 84:16 with the initially examined analogous benzyl ether were achieved.