82582-46-5

Upstream product

• 82293-79-6 (η5-C5H5)Re(NO)(PPh3)(CO2CH3) 
• 99921-93-4 (C₅H₅)Re(NO)(P(C₆H₅)3)(C(CH₂)OSi(CH₃)3) 
• 124-41-4 sodium methylate 
• 99921-92-3 (C₅H₅)Re(NO)(P(C₆H₅)3)(C(O)CH₂Si(CH₃)3) 

Downstream Products

• 82582-34-1 {(η5-C5H5)Re(NO)(PPh3)(vinylidene)}(CF3SO3) 
• 1493-13-6 trifluorormethanesulfonic acid 
• 93304-78-0 (C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃) 
• 93381-97-6 (C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)(CH₃) 
• 93304-83-7 (C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)^(1-)*Li⁽¹⁺⁾=[(C₅H₄(C(O)CH₃))Re(NO)(P(C₆H₅)3)]Li 

Relevant academic research and scientific papers

Reactions of chiral (α-methoxyvinyl)rhenium complexes (η5-C5H5)Re(NO)(PPh3)(C(OCH 3)=CHR) with alkyl halides. Efficient 1,3-asymmetrlc induction

α-Methoxyvinyl complexes (Z)-(η5-C5H5)Re-(NO)(PPh 3)(C(OCH3)=CHR) are readily alkylated (C6H5CH2Br, CH3I) to give acyl complexes (η5-C5/sub

Synthesis and chemistry of chiral rhenium acyls (η-C5H5)Re(NO)(PPh3)(COR)

Rhenium acyls (η-C5H5)Re(NO)(PPh3)(COR) (R = CH3 (2), CH2CH3 (3), CH2-n-C8H17 (4), C6H5 (5), CH2C6H5 (6), CH2CH2C6H5 (7), CH=CH2 (8), CH2CH=CH2 (9)) are prepared in high yield by RMgX attack upon (η-C5H5)Re(NO)(PPh3)(COOCH3) (1). Acyl (η-C5H5)Re(NO)(PPh3)(COC≡CCH 3) (10) is prepared by LiC≡CCH3 attack upon [(η-C5H5)Re(NO)(PPh3)(CO)] +BF4-. Acyls 2, 5, and 7 are also prepared in optically active form from optically active 1. These compounds are characterized by IR, 1H NMR, 13C NMR, and (when optically active) ORD and CD. They are shown to undergo high-yield (1) BH3 reduction ((-)-(R)-2, 4, (+)-(R)-5, 7) to the corresponding alkyls (η-C5H5)Re(NO)(PPh3)(CH2R), (2) methylation with CH3SO3F/NH4+ PF6- (2, 5) to methoxycarbenes [(η-C5H5)Re(NO)(PPh3)(=C(OCH 3)R)]+ PF6-, and (3) protonation with CF3SO3H (2, 3) to hydroxycarbenes [(η-C5H5)Re(NO)(PPh3)(=C(OH)R)] +CF3SO3-. Structures for the preferred conformers of 2-10 and their methylation and protonation products are suggested.