82736-52-5Relevant academic research and scientific papers
Palladium-catalyzed substitution of allylic fluorides
Hazari, Amaruka,Gouverneur, Ve,Brown, John M.
supporting information; body text, p. 1296 - 1299 (2009/06/30)
As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladiumcatalyzed substitution. Their activity towards this reaction fits in the series OCO2Me>OBz? F? OAc. The classic stereoretention mechanis
Stereoselective Synthesis of Vinylcyclopropanes via Palladium-Catalyzed Reactions
Baeckvall, J. E.,Vagberg, J. O.,Zercher, C.,Genet, J. P.,Denis, A.
, p. 5430 - 5435 (2007/10/02)
Vinylcyclopropanes were synthesized in a stereocontrolled manner from 1-acetoxy-4-chloro-2-alkenes.A stereospecific palladium-catalyzed substitution of the chloro group by dimethyl malonate anion and subsequent palladium-catalyzed cyclization afforded the
STEREOSPECIFIC PALLADIUM-CATALYZED 1,4-ACETOXYCHLORINATION OF 1,3-DIENES
Baeckvall, Jan-E.,Nordberg, Ruth E.,Nystroem, Jan-E.
, p. 1617 - 1620 (2007/10/02)
Palladium-catalyzed oxidation of 1,3-dienes in acetic acid in the presence of LiCl and LiOAc produces 1-acetoxy-4-chloro-2-alkenes in high selectivity.The 1,4-adducts were stereo- and regioselectively functionalized.
