82736-90-1Relevant academic research and scientific papers
HYPERVALENT IODINE IN ORGANIC SYNTHESIS. ACETAL FORMATION UNDER BASIC CONDITIONS AND CARBON DEUTERIATION OF THE ALDEHYDO GROUP
Moriarty, Robert M.,Hu, Henry
, p. 1537 - 1540 (1982)
Aldazines upon treatment with phenyliodosyl diacetate in CH3OH or CH3OD and NaOCH3 are converted smoothly into two equivalents of the corresponding aldehyde dimethylacetal with deuterium incorporation at the aldehydic carbon atom in the case of CH3OD.
NOVEL SUGAR-DERIVED GELATOR
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Paragraph 0144; 0145; 0146; 0148; 0149, (2015/02/18)
There is provided a novel gelator containing a sugar derivative. A gelator including a compound of Formula (1) or Formula (2): wherein each of R1 and R3 is independently a linear or branched alkyl group having a carbon atom number of 1 to 20, a cyclic C3-20 alkyl group, or a linear or branched alkenyl group having a carbon atom number of 2 to 20, n is 0 or an integer of 1 to 4, R2 is a hydrogen atom, a linear or branched alkyl group having a carbon atom number of 1 to 10, or an aryl group optionally having a substituent, and R4 and R5 are each a hydroxy group.
Tuning methyl 4,6-O-benzylidene α-D-glucopyranosides' gelation ability by minor group modifications
Abreu, Marlon F.,Salvador, Vítor T.,Vitorazi, Letícia,Gatts, Carlos E.N.,Dos Santos, Denise R.,Giacomini, Rosana,Cardoso, Sergio L.,Miranda, Paulo C.M.L.
, p. 69 - 78 (2012/07/02)
Ten methyl 4,6-O-benzylidene α-d-glucopyranosides were synthesized for the purpose of studying systematically the effect of small group changes at position 4 of the aromatic ring on the ability to gelate organic solvents. The gelation properties are discussed on the basis of small angle X-ray scattering (SAXS), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) measurements, and scanning electron microscopy (SEM) observations. Sol-gel transition temperatures were determined simultaneously by DSC and temperature-dependent FTIR measurements. The current study emphasizes that carbohydrates furnish not only valuable information about structural requirements for organogelator design, but also for molecular assembly systems in general.
