82736-93-4Relevant academic research and scientific papers
Reductive openings of benzylidene acetals revisited: A mechanistic scheme for regio- and stereoselectivity
Johnsson, Richard,Ohlin, Markus,Ellervik, Ulf
supporting information; experimental part, p. 8003 - 8011 (2011/03/18)
Despite the importance of regioselective reductive openings of cyclic acetals, mechanistic details are scarce. In this study 4,6-O-benzylidene acetals were used as model compounds for deciphering the mechanism of regioselective openings using a variety of
HYPERVALENT IODINE IN ORGANIC SYNTHESIS. ACETAL FORMATION UNDER BASIC CONDITIONS AND CARBON DEUTERIATION OF THE ALDEHYDO GROUP
Moriarty, Robert M.,Hu, Henry
, p. 1537 - 1540 (2007/10/02)
Aldazines upon treatment with phenyliodosyl diacetate in CH3OH or CH3OD and NaOCH3 are converted smoothly into two equivalents of the corresponding aldehyde dimethylacetal with deuterium incorporation at the aldehydic carbon atom in the case of CH3OD.
