82768-70-5

Upstream product

• 82707-14-0 methyl 6-aldehydo-3-O-benzyl-2,4-dideoxy-2,4-di-C-methyl-α-D-gulopyranoside 
• 19493-09-5 Methylenetriphenylphosphorane 
• 100-39-0 benzyl bromide 
• 82707-05-9 methyl 3-O-benzyl-2,4-dideoxy-2,4-di-C-methyl-α-D-gulopyranoside 
• 82707-13-9 methyl 3-O-acetyl-4,6-O-benzylidene-2-C-methyl-α-D-allopyranoside 
• 82731-51-9 methyl 3-O-acetyl-6-O-t-butyldiphenylsilyl-2-deoxy-C-methyl-α-D-allopyranoside 
• 82731-52-0 methyl 3-O-acetyl-6-O-t-butyldiphenylsilyl-2-deoxy-2-C-methyl-α-D-ribo-hexapyranoside-3-ulose 
• 82707-04-8 methyl 3-O-benzyl-6-O-t-butyldiphenylsilyl 2,4-dideoxy-2,4-di-C-methyl-α-D-gulopyranoside 
• 82731-53-1 (2S,4R,5R,6S)-2-Hydroxymethyl-6-methoxy-3,5-dimethyl-tetrahydro-pyran-4-ol 
• 75879-81-1 Methyl 4,6-O-Benzylidene-2-deoxy-2-C-methyl-α-D-allopyranoside 
• 82707-03-7 (2S,4S,5R,6S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-6-methoxy-5-methyl-3-methylene-tetrahydro-pyran-4-ol 

Downstream Products

• 82707-15-1 (2S,3S,4S,5R)-3-Benzyloxy-2,4-dimethyl-heptane-1,5-diol 
• 82707-16-2 (3R,4S,6S)-5-Benzyloxy-4,6-dimethyl-7-trityloxy-heptan-3-ol 
• 82707-06-0 (4R,6S)-5-Benzyloxy-4,6-dimethyl-7-trityloxy-heptan-3-one 
• 82707-10-6 (2S,3S,6S,7S,8S,9S)-8-Benzyloxy-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methoxy-3,5,7,9-tetramethyl-10-trityloxy-decane-4,6-diol 
• 82707-09-3 (2S,3S,4R,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 82707-09-3 (2S,3S,4R,6S,7R,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 82707-09-3 (2S,3S,4R,6R,7S,8S,9S)-3-Benzyloxy-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-9-methoxy-2,4,6,8-tetramethyl-1-trityloxy-decan-5-one 
• 82707-06-0 3-O-benzyl-2,4,6,7-tetradeoxy-5-keto-2,4-di-C-methyl-1-O-triphenylmethyl-L-lyxo-heptitol 
• 82707-16-2 3-O-benzyl-2,4,6,7-tetradeoxy-2,4-di-C-methyl-1-O-triphenylmethyl-D-gulo-heptitol 
• 82769-13-9 methyl 3-O-benzyl-2,4,6,7-tetradeoxy-2,4-di-C-methyl-α-D-gulo-heptopyranoside 

Relevant academic research and scientific papers

ASSEMBLY OF THE C19-C29 ALIPHATIC SEGMENT OF RIFAMYCIN S FROM D-DLUCOSE BY THE CHIRON APPROACH

We describe a stereocontrolled method for the construction of the aliphatic chain of rifamycin S, based on a strategy that utilizes carbohydrates as optically active precursors.