82769-01-5

Basic information

• Product Name: (1R,4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-2-enol
• Synonyms: (1R,4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-2-enol;(1R,4S)-1-methyl-4-(prop-1-en-2-yl)cyclohex-2-en-1-ol;(-)-Menthadienol;2-Cyclohexen-1-ol, 1-methyl-4-(1-methylethenyl)-, (1R-cis)-
• CAS NO: 82769-01-5
• Molecular Formula: C₁₀H₁₆O
• Molecular Weight: 152.23344
• Mol File: 82769-01-5.mol

Chemical Properties

• Boiling Point: 216.9±40.0 °C(Predicted)
• Appearance: /
• Density: 0.947±0.06 g/cm3(Predicted)
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
• PKA: 14.66±0.40(Predicted)
• Stability: Light Sensitive
• CAS DataBase Reference: (1R,4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-2-enol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-2-enol(82769-01-5)
• EPA Substance Registry System: (1R,4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-2-enol(82769-01-5)

Safety Data

• Hazardous Substances Data: 82769-01-5(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Industry:
(1R,4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-2-enol is used as a reagent in the synthesis of cannabinoids, which are pharmaceutical active agents for some dosage forms. Its unique structure allows it to be a key intermediate in the production of these bioactive compounds, contributing to the development of new medications with potential therapeutic benefits.
Used in Chemical Synthesis:
(1R,4S)-1-Methyl-4-(prop-1-en-2-yl)cyclohex-2-enol is also used as a reagent in the preparation of some pharmaceutical intermediates. Its versatility in chemical reactions makes it a valuable component in the synthesis of various complex organic molecules, which can be further utilized in the development of pharmaceuticals, agrochemicals, or other specialty chemicals.

Upstream product

• 138-86-3 limonene. 
• 1686-14-2 α-pinene epoxide 
• 5989-27-5 D-limonene 
• 74756-09-5 1α-hydroxy-2β-phenylseleno-trans-p-menth-8-ene 
• 106-25-2 Nerol 
• 106-24-1 Geraniol 
• 1195-92-2 Limonene oxide 

Downstream Products

• 68754-14-3 1-acetoxy-trans-p-mentha-2,8-diene 
• 16750-82-6 (S)-isopiperitenone 
• 6252-34-2 6-(1'-hydroxyisopropyl)-3-methyl-2-cyclohexenol 
• 83217-89-4 4(15)-eudesmene-1β,11-diol 
• 71697-77-3 6β-(2'-hydroxyisopropyl)-3-methyl-2-cyclohexenone 
• 14132-18-4 6,6,9-Trimethyl-3-pentyl-6a,7,10,10a-tetrahydro-6H-benzo[c]chromen-1-ol 
• 16849-50-6 tetrahydrocannabinol 
• 536697-79-7 abn-cannabidiol 
• 3556-78-3 cannabidiol 
• 43009-38-7 (6aS,10aR)-6,6,9-trimethyl-3-pentyl-6a,7,8,10a-tetrahydro-6H-benzo[c]chromen-1-ol 
• 6909-05-3 iso-Δ⁸-tetrahydrocannabinol 

Relevant articles and documents

Activated vs. pyrolytic carbon as support matrix for chemical functionalization: Efficient heterogeneous non-heme Mn(II) catalysts for alkene oxidation with H2O2

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Influence of the Br?nsted and Lewis acid sites on the catalytic activity and selectivity of Fe/MCM-41 system

The system Fe2O3/MCM-41, with high iron dispersion, was synthesized in order to introduce Lewis acid sites into the MCM-41 structure. Two calcination atmospheres (inert and oxidant) were used to produce iron nanoclusters with different structural properties. Besides, a silylation treatment was realized on both solids with the aim of neutralizing the Br?nsted acidity associated with the MCM-41 silanol groups. The samples were characterized by atomic absorption spectroscopy, X-ray diffraction at low angles, N2 adsorption, temperature-programmed reduction, Fourier transform infrared spectroscopy, nuclear magnetic resonance of 29Si, and M?ssbauer spectroscopy. The influence of the structural changes of the nanoclusters and the effect of the simultaneous presence of Lewis and Br?nsted acid sites were evaluated studying the product distribution from the α-pinene oxide isomerization reaction. It was determined that the Br?nsted acidity of the Fe/MCM-41 system has not the sufficient acid strength to modify the product distribution which is mainly governed by the Lewis sites.

Selective photosensitized oxidation and its catalytic regulation of monoterpene with molecular oxygen in different reaction media

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Abnormal Cannabidiols as agents for lowering intraocular pressure

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