828283-34-7Relevant articles and documents
Csp3Csp3 bond cleavage in the palladium-catalyzed aminohydroxylation of allylic hydrazones using atmospheric oxygen as the sole oxidant
Chen, Yu-Chen,Zhu, Ming-Kui,Loh, Teck-Peng
supporting information, p. 2712 - 2715 (2015/06/16)
A C-C bond cleavage was observed in the palladium-catalyzed aminohydroxylation of allylic hydrazones, using atmospheric oxygen as the sole oxidant. This reaction could also proceed in a one-pot manner, starting from keto-alkene compounds and phenylhydrazine.
Pyrazole-tethered arylphosphine ligands for Suzuki reactions of aryl chlorides: How important is chelation?
Mukherjee, Anuradha,Sarkar, Amitabha
, p. 9525 - 9528 (2007/10/03)
Pyrazole-derived bidentate ligands (P,N-donor) with bulky substituents at the 3-position of the pyrazole, 1b-d, were used with Pd2(dba) 3 to carry out efficient Suzuki coupling reactions with both aryl bromides and chlorides. Enhanced catalytic activity on account of steric crowding in the metal complex suggested participation of a chelated structure in the intermediate catalytic steps.