82916-73-2Relevant academic research and scientific papers
One pot conversion of alcohols to disulfides mediated by benzyltriethylammonium tetrathiomolybdate
Sinha, Surajit,Ilankumaran,Chandrasekaran
, p. 14769 - 14776 (2007/10/03)
A one pot conversion of alcohols to disulfides in good yields via the activation of a hydroxyl group with DCC or P(NMe2)3 / CCl4 followed by treatment with benzyltriethylammonium tetrathiomolybdate is reported.
Sulfur-Sulfur Bond Cleavage Processes. Selective Desulfurization of Trisulfides
Harpp, David N.,Smith, Roger A.
, p. 6045 - 6053 (2007/10/02)
The selectivity of sulfur removal in the desulfurization of trisulfides by tertiary phosphorus compounds has been investigated in detail.A mechanistic rationalization is proposed to account for central/terminal sulfur extrusion variation as a function of substrate structure and solvent polarity.
