82940-47-4

Upstream product

• 33210-00-3 4,5-dimethyl-2-(toluene-4-sulfonyl)-3,6-dihydro-2H-[1,2]thiazine 1-oxide 
• 176249-70-0 N-(2-bromo-2-propen-1-yl)-N-(2-propen-1-yl)-4-toluenesulfonamide 
• 127-65-1 chloroamine-T 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 98-59-9 p-toluenesulfonyl chloride 
• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 
• 4104-47-6 N-sulfinyl-p-toluenesulfonamide 
• 82940-43-0 C₁₉H₂₁NO₂S₂ 

Relevant academic research and scientific papers

Suppressed β-hydride elimination in palladium-catalyzed cascade cyclization-coupling reactions: An efficient synthesis of 3-arylmethylpyrrolidines

(formula presented) A novel type of palladium-catalyzed cascade cyclization-coupling reaction that proceeds with suppressed β-hydride elimination has been found. One of the N-sulfonyl oxygens is suggested to coordinatively stabilize an alkylpalladium inte

N-p-Toluenesulfonylpyrroles from 1,3-dienes

1,3-Dienes can be converted to N-p-toluenesulfonylpyrroles in two steps: 1) [4+2]-cycloaddition with N-sulfinyl-p-toluenesulfonamide and 2) conversion of the 3,6-dihydro-1,2-thiazine oxide adduct to a pyrrole using triethylamine-trimethylphosphite.

PERICYCLIC REACTIONS OF PSEUDO-TRIENES. ELECTROCYCLIZATION OF S-BUTADIENYL SULFILIMINES

N-Tosyl-S-butadienyl sulfilimines were prepared from butadienyl sulfides and were thermally converted into N-tosyl pyrroles, probably via cyclic azasulfonium ylides.