82959-19-1Relevant academic research and scientific papers
NOVEL OXY-PERFLUOROALKYLATION
Umemoto, Teruo,Kuriu, Yuriko,Nakayama, Shin-ichi
, p. 4101 - 4102 (1982)
(Perfluoroalkyl)phenyliodonium sulfonates underwent novel oxy-perfluoroalkylation with alkenes under oxygen atmosphere in the presence of a base.
One-pot reaction for the synthesis of fluorinated β-diketones
Huang, Wei-yuan,Wu, Yong-ming
, p. 179 - 183 (2007/10/02)
Fluorinated β-diketones have been synthesized in high yield from the one-pot reaction of silyl enol ethers with perfluoroalkyl iodides initiates with Na2S2O4/NaHCO3, followed by treatment with diethylamine and acid hydrolysis.
ELECTROCHEMICAL SYNTHESIS OF PERFLUOROALKYLACETONES
Vol'pin, I. M.,Kurykin, M. A.,Grinberg, V. A.,Vasil'ev, Yu. B.,German, L. S.
, p. 1395 - 1400 (2007/10/02)
The interaction of electrochemically generated radicals in the electrolysis of the perfluorocarboxylic acids RFCF2COOH (I), where RF = F (a), CF3 (b), C2F5 (c), C3F7 (d), C5F11 (e). and C7F15 (f), with isoprenyl acetate (II) was studied.The dependence of the results of the electrolysis on the adsorption capacity of the anode permits the proposition that the interaction of (II) with the ECG-radicals occurs close to the surface of the electrode.The yield of the perfluoroalkylacetones comprised 30-37percent.
A NEW METHOD FOR THE PREPARATION OF α-(PERFLUOROALKYL) CARBONYL AND γ-(PERFLUOROALKYL)-α,β-UNSATURATED CARBONYL COMPOUNDS
Umemoto, Teruo,Kuriu, Yuriko,Nakayama, Shin-ichi,Miyano, Osamu
, p. 1471 - 1474 (2007/10/02)
RfI(Ph)OSO2CF3 or RfI(Ph)OSO3H smoothly reacted with various trimethylsilyl enol ethers under mild conditions to give α(perfluoroalkyl) carbonyl and γ=)perfluoroalkyl)-α,β-unsaturated carbonyl compounds in high yields.
