82976-54-3

Upstream product

• 83960-80-9 3-(2-Carboxy-5-methoxy-phenyl)-propionsaeure 
• 1078-19-9 6-methoxy-3,4-dihydro-1(2H)-naphthalenone 
• 16821-32-2 6-methoxy-1,2,3,4-tetrahydronaphthalen-1-ol 
• 52178-91-3 7-methoxy-1,2-dihydronaphthalene 

Downstream Products

• 853061-12-8 2-(3-hydroxy-propyl)-4-methoxy-benzaldehyde 
• 853061-32-2 (E)-9-{2-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-6-fluoro-3-oxo-non-6-enoic acid methyl ester 
• 853062-11-0 2-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-1-[(E)-3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-4-methoxy-benzene 
• 853061-29-7 (E)-5-{2-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-2-fluoro-pent-2-enoic acid ethyl ester 
• 853061-31-1 tert-Butyl-{(E)-3-[2-((E)-5-chloro-4-fluoro-pent-3-enyl)-4-methoxy-phenyl]-allyloxy}-diphenyl-silane 
• 853061-30-0 (E)-5-{2-[(E)-3-(tert-Butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-2-fluoro-pent-2-en-1-ol 
• 894784-27-1 (E)-9-{2-[(E)-3-(2,2-Dimethyl-propionyloxy)-propenyl]-5-methoxy-phenyl}-6-fluoro-3-oxo-non-6-enoic acid methyl ester 
• 853061-26-4 3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propan-1-ol 
• 853061-33-3 (E)-6-Fluoro-9-[2-((E)-3-hydroxy-propenyl)-5-methoxy-phenyl]-3-oxo-non-6-enoic acid methyl ester 
• 853061-28-6 3-{2-[3-(tert-butyl-diphenyl-silanyloxy)-propenyl]-5-methoxy-phenyl}-propionaldehyde 
• 853061-24-2 3-{2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methoxy-phenyl}-acrylic acid ethyl ester 
• 853061-22-0 3-{2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methoxy-phenyl}-prop-2-en-1-ol 
• 853061-14-0 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-methoxy-benzaldehyde 
• 65272-96-0 3-(2-methyl-5-methoxyphenyl)propanol 

Relevant academic research and scientific papers

Total synthesis of 14β-fluorosteroids via a transannular Diels-Alder reaction

14β-Fluorosteroids 3 and 4 were synthesized to give a new class of unnatural cardenolides. The total synthesis of racemic 14β-fluorosteroids was accomplished using a highly diastereoselective transannular Diels-Alder reaction on a trans-cis-cis macrocycli

BORON ANNULATION: SYNTHESIS OF TRANS-DECALIN NATURAL PRODUCT SYNTHONS

Boron annulation of olefines 3, 4 and 14 has afforded decalin synthons 1 and 2 and perhydrophenanthrone 15, respectively.The A, B ring juncture of 15 and the ring systems of 1 and 2 were found to be trans.