Canadian Journal of Chemistry p. 29 - 48 (2006)
Update date:2022-07-29
Topics:
Beaubien, Sylvie
Deslongchamps, Pierre
14β-Fluorosteroids 3 and 4 were synthesized to give a new class of unnatural cardenolides. The total synthesis of racemic 14β-fluorosteroids was accomplished using a highly diastereoselective transannular Diels-Alder reaction on a trans-cis-cis macrocycli
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