83960-80-9

Upstream product

• 52178-91-3 7-methoxy-1,2-dihydronaphthalene 
• 132432-05-4 2-furfurylidene-6-methoxy-3,4-dihydronaphthalen-1(2H)-one 
• 1078-19-9 6-methoxy-3,4-dihydro-1(2H)-naphthalenone 
• 67-64-1 acetone 
• 873422-55-0 5-methoxy-1-oxo-indan-2-carbonitrile 
• 952006-66-5 5-methoxy-1-oxo-indan-2-carbaldehyde 
• 16821-33-3 7-methoxy-3-(6'-methoxy-1',2',3',4',-tetrahydronaphth-1'-yl)-1,2-dihydronaphthalene 
• 70157-84-5 6-methoxy-1,2,3,4-tetrahydronaphthalen-1-yl acetate 
• 69841-41-4 14α,17β-Diacetoxy-3-methoxy-8,14-secoestra-1,3,5(10),9(11)-tetraen 
• 83998-55-4 17β-Acetoxy-3-methoxy-8,14-secoestra-1,3,5(10),9(11)-tetraen-14-on 
• 25221-98-1 2-[(2E)-2-(6-methoxy-3,4-dihydronaphthalen-1(2H)-ylidene)-ethyl]-2-methylcyclopentane-1,3-dione 
• 16821-32-2 6-methoxy-1,2,3,4-tetrahydronaphthalen-1-ol 

Downstream Products

• 136035-99-9 4-Methoxy-2-(2-methoxycarbonyl-ethyl)-benzoic acid methyl ester 
• 82976-54-3 3-(2-Hydroxymethyl-5-methoxy-phenyl)-propan-1-ol 
• 5111-70-6 5-methoxy-1-indanone 
• 65272-96-0 3-(2-methyl-5-methoxyphenyl)propanol 

Relevant academic research and scientific papers

Synthetic Investigations on Illudinine: A New Synthesis of Methyl 8-Methoxy-2,2-dimethyl-7-oxo-1,2,3,5,6,7-hexahydro-s-indacene-4-carboxylate

A new strategy for the total synthesis of methyl 8-methoxy-2,2-dimethyl-7-oxo-1,2,3,5,6,7,-hexahydro-s-indacene-4-carboxylate 4, a key intermediate in the synthesis of illudalanes, is reported.The key step in this strategy is a new method of preparation o

Prostaglandins and Prostaglandin Intermediates. Oxidative Cleavage of Olefins by Ozonization and Oxidation in the Solvent System Acetone/tert. Butanol - a Method for Preparation of Substituted Cyclopentyl Acetic Acids

Oxidative cleavage of olefinic double bonds by ozonization in acetone in the presence of tert. butanol followed by oxidation with JONES' reagent in the same solvent system gives carboxylic acids and/or ketones in good yields.Acetic acid or water can be used instead of tert. butanol with the same success.This "one-pot" procedure was developed in connection with the synthesis of intermediates for the preparation of 8-methyl-prostaglandin C2.

BORON ANNULATION: SYNTHESIS OF TRANS-DECALIN NATURAL PRODUCT SYNTHONS

Boron annulation of olefines 3, 4 and 14 has afforded decalin synthons 1 and 2 and perhydrophenanthrone 15, respectively.The A, B ring juncture of 15 and the ring systems of 1 and 2 were found to be trans.