82994-36-3Relevant academic research and scientific papers
INFLUENCE OF THE CONSTRAINT OF BRIDGEHEAD STRUCTURE ON PHOSPHORUS REACTIVITY IN THE 1-PHOSPHABICYCLOOCTANE SYSTEM
Quin, Louis D.,Spence, Sharon C.
, p. 2529 - 2532 (1982)
Nucleophiles attack the methiodide of the 3,4-benzo derivative of the title system to displace the P-methyl group in preference to the benzylic moiety.The trigonal bipyramidal intermediates (as well as a stable dioxyphosphorane) appear to undergo rapid isomerization.
