INFLUENCE OF THE CONSTRAINT OF BRIDGEHEAD STRUCTURE ON PHOSPHORUS REACTIVITY IN THE 1-PHOSPHABICYCLOOCTANE SYSTEM

DOI: 10.1016/S0040-4039(00)87387-6

Source and publish data:

Tetrahedron Letters p. 2529 - 2532 (1982)

Update date:2022-08-02

Topics:

Authors:

Quin, Louis D.

Spence, Sharon C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)87387-6

Nucleophiles attack the methiodide of the 3,4-benzo derivative of the title system to displace the P-methyl group in preference to the benzylic moiety.The trigonal bipyramidal intermediates (as well as a stable dioxyphosphorane) appear to undergo rapid isomerization.

Full text of DOI:10.1016/S0040-4039(00)87387-6

Products guided by the article

Product name:9-Benzyl-1,11-dimethyl-9-phosphonia-tricyclo[7.2.1.0^2,7]dodeca-2,4,6-triene; bromide

Cas No:82994-36-3

R&D Labs maybe for 82994-36-3

Jiangsu Institute of Ecomones Co., Ltd

website:http://www.jsmone.com

Contact:+86-519-82821700

Address:95 Huanyuan N. Road, Jintan, Jiangsu, China
ZHEJIANG CHEMICAL INDUSTRY INSTITUTE TECHNOLOGY CO.,LTD(expird)

Contact:86-575-82730298

Address:shangyu
Tianjin Bright Future Technology Co., Ltd

Contact:0086-22-58016666

Address:NO.136 DongTeng Lake Street Tianjin Economic and Technology Development Area,Tainjin,China
suzhou chukai pharmateach co,.ltd

Contact:86-512-88812511

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Qingdao Kingway Pharmtech Co., Ltd.

Contact:86-532-87118899

Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China

Relevant to this article

ORGANODIMAGNESIUM DERIVATIVES OF THIOPHENE. 4. REACTION OF ORGANODIMAGNESIUM DERIVATIVES OF THIOPHENES THAT CONTAIN ARYL SUBSTITUENTS IN THE RING β POSITION WITH DIETHYL OXALATE

Doi:10.1007/BF00506143
(1982)
Synthesis of nitroxide derivatives of alkylnitrosourea

Doi:10.1007/BF00698442
(1993)
A new approach to the synthesis of 2-aryl-4-halomethyl-5-methyl-1,3- oxazoles by highly regioselective direct halogenation with NBS or NCS/MeCN

Doi:10.1055/s-2004-834862
(2004)
Telluration of seleno- and chloroiminium salts leading to various telluroamides, and their structure and NMR properties

Doi:10.1016/j.jorganchem.2006.03.045
(2007)
Activation of Small Molecules by the Metal-Amido Bond of Rhodium(III) and Iridium(III) (η⁵-C₅Me₅)M-Aminopyridinate Complexes

Doi:10.1021/acs.inorgchem.7b02283
(2018)
Thermal Reaction of Phenylnitrene with Sulfides

Doi:10.1039/c39820000763
(1982)

Article Doi