INFLUENCE OF THE CONSTRAINT OF BRIDGEHEAD STRUCTURE ON PHOSPHORUS REACTIVITY IN THE 1-PHOSPHABICYCLOOCTANE SYSTEM

DOI: 10.1016/S0040-4039(00)87387-6

Source and publish data:

Tetrahedron Letters p. 2529 - 2532 (1982)

Update date:2022-08-02

Topics:

Authors:

Quin, Louis D.

Spence, Sharon C.

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Article abstract of DOI:10.1016/S0040-4039(00)87387-6

Nucleophiles attack the methiodide of the 3,4-benzo derivative of the title system to displace the P-methyl group in preference to the benzylic moiety.The trigonal bipyramidal intermediates (as well as a stable dioxyphosphorane) appear to undergo rapid isomerization.

Full text of DOI:10.1016/S0040-4039(00)87387-6

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