830-42-2

Upstream product

• 98-60-2 4-chlorobenzenesulfonyl chloride 
• 107-11-9 1-amino-2-propene 
• 1017238-73-1 N-allyl-4-chlorobenzenesulfinamide 

Downstream Products

• 669062-09-3 methyl N-(3-(N-(2-propen-1-yl)(4-chlorophenyl)sulfonamidomethyl)benzoyl)-O-methyl-2-(2-propen-1-yloxy)tyrosinate 
• 946076-64-8 ethyl 7-(4-chlorobenzenesulfonylamino)-6-ethoxythiocarbonylsulfanyl-3-oxoheptanoate 
• 946076-65-9 O-ethyl S-[1-(4-chlorobenzenesulfonylaminomethyl)-4-oxo-5,5,5-trifluoropentyl] dithiocarbonate 
• 98-64-6 4-Chlorobenzenesulfonamide 
• 1208003-96-6 6-chloro-4-methyl-3,4-dihydro-2H-benzo[1,2]thiazine 1,1-dioxide 
• 1208004-02-7 4-chloro-N-(2-fluoropropyl)-benzenesulfonamide 
• 1429938-82-8 C₁₄H₁₅ClN₂O₃S 
• 1042039-70-2 dithiocarbonic acid S-[1-[(4-chloro-benzenesulfonylamino)-methyl]-3-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-propyl] ester O-ethyl ester 
• 946076-66-0 O-ethyl S-[1-(4-chlorobenzenesulfonylaminomethyl)-4-methoxyimino-5,5,5-trifluoropentyl] dithiocarbonate 
• 946076-42-2 O-ethyl S-[1-(N-acetyl-N-(4-chlorobenzenesulfonyl)aminomethyl)-5,5,5-trifluoro-4-methoxyiminopentyl] dithiocarbonate 
• 946076-41-1 N-acetyl-N-[5'-acetoxy-2'-ethoxythiocarbonylsulfanyl-6,6,6-trifluorohex-4-en-1-yl]-4-chlorobenzenesulfonamide 
• 946076-37-5 ethyl 7-(N-acetyl-N-(4-chlorobenzenesulfonyl)amino)-6-ethoxythiocarbonylsulfanyl-3-oxoheptanoate 
• 66897-40-3 N-Allyl-4-chloro-N-(2,4-dichloro-benzoyl)-benzenesulfonamide 

Relevant academic research and scientific papers

Rhodium(iii)-catalyzed oxidative olefination of N-allyl sulfonamides

Rhodium(iii)-catalyzed oxidative couplings between N-sulfonyl allylamines and activated olefins have been achieved. Only olefination occurred for acrylates, and the butadiene product can be further cyclized under palladium-catalyzed aerobic conditions. The coupling with N,N-dimethylacrylamide followed a cyclization pathway.

Mild and general method for the synthesis of sulfonamides

Reaction of methyl sulfinates with lithium amides followed by 3-chloroperoxybenzoic acid oxidation of the resulting sulfinamides provides primary, secondary, and tertiary alkane-, arene-and heteroarenesulfonamides in high yields. This constitutes a mild and facile experimental protocol that avoids the use of hazardous, unstable, or volatile reagents and does not affect the configurational stability of the amines. Georg Thieme Verlag Stuttgart.

Synthesis of Diverse Macrocyclic Peptidomimetics Utilizing Ring-Closing Metathesis and Solid-Phase Synthesis

The synthesis of a range of highly functionalized peptidomimetic macrocycles has been accomplished using ring-closing metathesis and enyne tandem cross-metathesis-ring-closing metathesis reactions. This approach gives access to rigidified macrocycles mode