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831-51-6

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831-51-6 Usage

General Description

3-amino-5-nitrosalicylic acid is a chemical compound with the molecular formula C7H6N2O5. It is a derivative of salicylic acid and is commonly used as a colorimetric reagent to detect the presence of nitrite ions in solution. The compound has a yellow to orange appearance and is soluble in water. It works by reacting with nitrite ions to form a diazonium salt, which can then be coupled with other compounds to produce a colored product. This reaction is often used in laboratory settings to quickly and easily detect the presence of nitrite ions, which can be indicative of various environmental and health concerns. Additionally, 3-amino-5-nitrosalicylic acid is also employed in the synthesis of pharmaceuticals and other organic compounds due to its versatile chemical properties.

Check Digit Verification of cas no

The CAS Registry Mumber 831-51-6 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 8,3 and 1 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 831-51:
(5*8)+(4*3)+(3*1)+(2*5)+(1*1)=66
66 % 10 = 6
So 831-51-6 is a valid CAS Registry Number.
InChI:InChI=1/C7H6N2O5/c8-5-2-3(9(13)14)1-4(6(5)10)7(11)12/h1-2,10H,8H2,(H,11,12)

831-51-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-amino-2-hydroxy-5-nitrobenzoic acid

1.2 Other means of identification

Product number -
Other names 3-Amino-5-nitrosalicylic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:831-51-6 SDS

831-51-6Synthetic route

3,5-dinitrosalicylic acid
609-99-4

3,5-dinitrosalicylic acid

3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

Conditions
ConditionsYield
bei partieller Reduktion;
With ammonium sulfide; ammonia
3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

3,5‐diaminosalicylic acid
112725-89-0

3,5‐diaminosalicylic acid

Conditions
ConditionsYield
With sodium tetrahydroborate; C54H50Cl2N2O3Ru2 In ethanol at 20℃; for 3h;80%
phosgene
75-44-5

phosgene

3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

5-nitro-2-oxo-2,3-dihydro-benzoxazole-7-carboxylic acid

5-nitro-2-oxo-2,3-dihydro-benzoxazole-7-carboxylic acid

Conditions
ConditionsYield
With alkali
phosgene
75-44-5

phosgene

3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

5,5'-diamino-2,2'-dihydroxy-3,3'-ureylene-di-benzoic acid

5,5'-diamino-2,2'-dihydroxy-3,3'-ureylene-di-benzoic acid

Conditions
ConditionsYield
nachfolgend Reduktion;
3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

3-carboxy-2-hydroxy-5-nitro-benzenediazonium-betaine

3-carboxy-2-hydroxy-5-nitro-benzenediazonium-betaine

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite
3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

acetic anhydride
108-24-7

acetic anhydride

3-acetylamino-2-hydroxy-5-nitro-benzoic acid
54670-12-1

3-acetylamino-2-hydroxy-5-nitro-benzoic acid

3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

1-chloro-2,4-dinitro-benzene
97-00-7

1-chloro-2,4-dinitro-benzene

3-(2,4-dinitro-anilino)-2-hydroxy-5-nitro-benzoic acid

3-(2,4-dinitro-anilino)-2-hydroxy-5-nitro-benzoic acid

3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

A

3-bromo-2-hydroxy-5-nitro-benzoic acid
57688-24-1

3-bromo-2-hydroxy-5-nitro-benzoic acid

B

2.6-dibromo-nitro-phenol

2.6-dibromo-nitro-phenol

Conditions
ConditionsYield
With hydrogen bromide Reaktion ueber mehrere Stufen;
3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: hydrobromic acid / Reaktion ueber mehrere Stufen
2: tin; hydrochloric acid
3: water; sodium nitrite / Behandeln der entstandenen Diazoverbindung mit absol. Alkohol
4: water / 180 °C
View Scheme
3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

3-bromosalicylic acid
3883-95-2

3-bromosalicylic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: hydrobromic acid / Reaktion ueber mehrere Stufen
2: tin; hydrochloric acid
3: water; sodium nitrite / Behandeln der entstandenen Diazoverbindung mit absol. Alkohol
View Scheme
3-amino-5-nitrosalicylic acid
831-51-6

3-amino-5-nitrosalicylic acid

5-amino-3-bromosalicylic acid
54669-99-7

5-amino-3-bromosalicylic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hydrobromic acid / Reaktion ueber mehrere Stufen
2: tin; hydrochloric acid
View Scheme

831-51-6Relevant articles and documents

Selective partial hydrogenation of dinitrobenzenes to nitroanilines catalyzed by Ru/C

Hou, Jie,Ma, Yonghuan,Li, Yuhan,Guo, Fang,Lu, Lianhai

scheme or table, p. 974 - 975 (2009/04/06)

Ru/C was found to be a highly effective catalyst for the selective partial hydrogenation of a range of dinitrobenzenes to their corresponding nitroanilines with excellent selectivity under mild conditions. Furthermore, the effect from other substitute groups of dinitrobenzenes on partial hydrogenation was also explored in this study. Copyright

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