83126-69-6Relevant academic research and scientific papers
Synthesis of chiral 2-arylpropenoic esters by the palladium catalyzed carbonylation of arylacetylenes
Monteiro, Adriano L.,Lando, Vanusa R.,Gasparini, Vanessa
, p. 3605 - 3611 (1997)
A simple method is described for the synthesis of chiral 2-arylpropenoic esters by carbonylation of arylacetylenes in the presence of chiral alcohols catalyzed by palladium complexes under mild conditions (10 atm, 100°C, 2h) with high yields.
Stereochemistry of 1,3-Eliminative Cyclopropanation
Nishiyama, Kazuyoshi,Inouye, Yuzo
, p. 1027 - 1034 (2007/10/02)
The estereochemistry of 1,3-eliminative cyclopropanation was established in the NaH-catalyzed condensation system involving carbanionic reagents with chlorine and phosphate as the leaving group.It was proved by means of product analysis that the steric co
