Synthesis of chiral 2-arylpropenoic esters by the palladium catalyzed carbonylation of arylacetylenes

Article abstract of DOI:10.1080/00397919708007083

A simple method is described for the synthesis of chiral 2-arylpropenoic esters by carbonylation of arylacetylenes in the presence of chiral alcohols catalyzed by palladium complexes under mild conditions (10 atm, 100°C, 2h) with high yields.

Full text of DOI:10.1080/00397919708007083

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Synthetic Communications: An
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Synthesis of Chiral 2-
Arylpropenoic Esters by
the Palladium Catalyzed
Carbonylation of
Arylacetylenes
Adriano L. Monteiro a , Vanusa R. Lando a & Vanessa
Gasparini a
a Grupo de Catálise, Instituto de Química,
Universidade Federal do Rio Grande do Sul , Av.
Bento Gonçalves, 9500, CEP 91591—970, Porto
Alegre, Brazil
Published online: 22 Aug 2006.
To cite this article: Adriano L. Monteiro , Vanusa R. Lando & Vanessa Gasparini
(1997) Synthesis of Chiral 2-Arylpropenoic Esters by the Palladium Catalyzed
Carbonylation of Arylacetylenes, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 27:20, 3605-3611, DOI:
10.1080/00397919708007083
To link to this article: http://dx.doi.org/10.1080/00397919708007083
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