832-10-0

Basic information

• Product Name: CYCLOTRIDECANONE
• Synonyms: CYCLOTRIDECAN-1-ONE;CYCLOTRIDECANONE;Cyclotridecanonetech;Cyclotridecane-1-one
• CAS NO: 832-10-0
• Molecular Formula: C₁₃H₂₄O
• Molecular Weight: 196.33
• EINECS: 212-615-3
• Product Categories: C13 to C14;Carbonyl Compounds;Ketones
• Mol File: 832-10-0.mol
• Article Data: 14

Chemical Properties

• Melting Point: 30-31 °C(lit.)
• Boiling Point: 146 °C11 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 0.927 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.00273mmHg at 25°C
• Refractive Index: n20/D 1.479(lit.)
• CAS DataBase Reference: CYCLOTRIDECANONE(CAS DataBase Reference)
• NIST Chemistry Reference: CYCLOTRIDECANONE(832-10-0)
• EPA Substance Registry System: CYCLOTRIDECANONE(832-10-0)

Safety Data

• Safety Statements: 24/25
• WGK Germany: 3
• Hazardous Substances Data: 832-10-0(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 96, p. 6510, 1974 DOI: 10.1021/ja00827a042The Journal of Organic Chemistry, 32, p. 962, 1967

InChI:InChI=1/C13H24O/c14-13-11-9-7-5-3-1-2-4-6-8-10-12-13/h1-12H2

Upstream product

• 186581-53-3 diazomethane 
• 830-13-7 cyclododecanone 
• 7735-44-6 Tetradecandisaeuredinitril 
• 32400-07-0 methylenecyclodecane 
• 5601-68-3 cyclotridecyne 
• 19812-63-6 diethyl tetradecanedioate 
• 3661-77-6 cycloheptadecanone 
• 2550-52-9 cyclohexadecanone 
• 3603-99-4 cyclotetradecanone 
• 502-72-7 cyclopentadecanone 
• 1370649-97-0 methyl (1Z)-cyclopentadec-1-ene-1-carboxylate 
• 1370649-96-9 methyl (1Z)-cyclotetradec-1-ene-1-carboxylate 
• 1370649-95-8 methyl (1Z)-cyclotridec-1-ene-1-carboxylate 
• 1333501-89-5 methyl (1Z)-cyclohexadec-1-ene-1-carboxylate 

Downstream Products

• 75311-77-2 2-Methylcyclotetradecanon 
• 1502-06-3 cyclodecanone 
• 878-13-7 cycloundecanone 
• 63134-81-6 methyl (1Z)-cycloundec-1-ene-1-carboxylate 
• 830-13-7 cyclododecanone 
• 10329-91-6 cyclotridecanol 
• 505-52-2 brassylic acid 
• 3603-99-4 cyclotetradecanone 
• 91652-59-4 C₃₇H₅₈N₄O₇S₂ 
• 245119-68-0 [3-(azacyclotetradec-1-yl)-propyl]-(3-benzyloxycarbonylamino-propyl)-carbamic acid benzyl ester 
• 295-18-1 azacyclotetradecane 
• 22442-01-9 3-methylcyclopentadecenone 
• 3661-77-6 cycloheptadecanone 
• 956-82-1 3-methylcyclopentadecanone 

Relevant articles and documents

Cyclopentadecanon preparation method

The invention discloses a cyclopentadecanon preparation method. Specifically, the method comprises the following steps: (a) in an inert solvent, reacting formula IV compound with diazomethane to formformula III compound; (b) in the inert solvent, reacting the formula III compound with the diazomethane to form formula II compound; (c) in the inert solvent, reacting the formula II compound with thediazomethane to form formula I compound. The method disclosed by the invention has the characteristics of ability in accurately controlling pressure and material feeding, ability in greatly improvingreaction speed, stable reaction yield, high product purity and low technological cost; thus, the method has a wide application prospect.

Gene encoding cyclododecanone monooxygenase

The invention relates to a new strain of Pseudomonas putida (designated as HI-70) and to the isolation, cloning, and sequencing of a cyclododecanone monooxygenase-encoding gene (named cdnB) from said strain. The invention also relates to a new cyclododecanone monooxygenase and to a method of use of the cyclododecanone monooxygenase-encoding gene.

Silica Gel Supported γ-Picolinium Chlorochromate; a New and Efficient Reagent for Selective Conversion of Alcohols and Oximes into Carbonyl Compounds under Mild and Non-Aqueous Conditions

The preparation of silica gel supported γ-picolinium chlorochromate and its application as an efficient reagent for selective oxidation of oximes and alcohols into carbonyl compounds is reported. The trimethylsilyloxy and ester groups survived under the reaction conditions.