832-81-5Relevant articles and documents
Synthesis and structural characterization of arene d6 metal complexes of sulfonohydrazone and triazolo ligands: High potency of triazolo derivatives towards DNA binding
Shadap, Lathewdeipor,Joshi, Nidhi,Poluri, Krishna Mohan,Kollipara, Mohan Rao,Kaminsky, Werner
, p. 302 - 312 (2018)
Complexation of [(p-cymene)RuCl2]2 and [Cp?MCl2]2 (M = Rh/Ir) with chelating ligand 4-methylbenzenesulfonohydrazone ligands (L1 and L3) resulted in the formation of mononuclear cationic complexes having PF6
Nitrous oxide as a diazo transfer reagent: The synthesis of triazolopyridines
Landman, Iris R.,Fadaei-Tirani, Farzaneh,Severin, Kay
, p. 11537 - 11540 (2021/11/16)
Nitrous oxide is a potential diazo transfer reagent, but its applications in organic chemistry are scarce. Here, we show that triazolopyridines and triazoloquinolines are formed in the reactions of metallated 2-alkylpyridines or 2-alkylquinolines with N2O. The reactions can be performed under mild conditions and give synthetically interesting triazoles in moderate to good yields.
Method for synthesizing [1,2,3]triazole[1,5-a]pyridines compound through non-catalyst N-N coupling reaction
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Paragraph 0032-0037; 0048-0052; 0063-0065, (2019/04/04)
The invention relates to a method for synthesizing [1,2,3]triazole[1,5-a]pyridines compound through non-catalyst N-N coupling reaction. The invention discloses an efficient method for synthesizing a product at one step without using a catalyst under a mild condition from a 2-pyridylamine compound and nitroso tert-butyl ester as a mild nitrogen atom source. The method is free from the catalyst, thereaction step is reduced, the condition is extremely mild, the efficiency is high, and the later modification can be performed on the biological active molecular, thereby facilitating the industrialproduction of [1,2,3]triazole[1,5-a]pyridines compound.