83230-73-3

Upstream product

• 103203-83-4 3-(allyloxy)benzoic acid 
• 79250-46-7 methyl 3-(prop-2-enyloxy)benzoate 

Downstream Products

• 69819-26-7 3-allyloxy-N-(5-nitro-thiazol-2-yl)-benzamide 
• 90531-43-4 3-Allyloxy-benzoic acid 2-hydroxy-3-isopropylamino-propyl ester 
• 1023287-45-7 3-(allyloxycarbonyl)phenyl 3-allyloxybenzoate 
• 1023287-47-9 2-[3-allyloxy-3-oxopropyl]phenyl 3-allyloxybenzoate 
• 1214267-23-8 allyl 2-[(3-allyloxybenzoyl)amino] benzoate 
• 40359-32-8 3-allyloxy-benzaldehyde 
• 67698-61-7 3-O-propoxybenzaldehyde 

Relevant academic research and scientific papers

Rh(iii)-Catalyzed intramolecular redox-neutral cyclization of alkenes via C-H activation

Biologically interesting fused oligocyclic lactams have been prepared via an intramolecular redox-neutral cyclization process. By the proper choice of the substrates with a wide variety of tethered olefins, the less favored C-H bond can be activated and f

A practical in situ generation of the schwartz reagent. reduction of tertiary amides to aldehydes and hydrozirconation

A new, highly efficient in situ protocol (Cp2ZrCl2/LiAlH(OBu-t)3) is described for the generation of the Schwartz reagent which provides a convenient method for the amide to aldehyde reduction and the regioselective hydrozirconation-iodination of alkynes and alkenes. Highlighted are chemoselective reductions of benzamides derived by directed ortho metalation (DoM) chemistry, allowing the synthesis of valuable 1,2,3-substituted benzaldehydes. The single-step, three-component process proceeds in a very short reaction time, shows excellent functional group compatibility, and uses inexpensive and long-storage stable reducing reagents.

A synthetic study of dibenzo-aromatic macrolactams

Efforts to generate benzenoid macrolactams in the development of hybrid molecules as New Chemical Entities are described. The olefin metathesis protocol was adopted in facilitating the cyclization process.

A one-pot synthesis of 2-Aryl-4,5-anti-diphenyloxazolines

A one-pot procedure for the synthesis of oxazolines was developed. An amino alcohol was coupled with benzoyl chlorides in the presence of triethylamine to produce a -hydroxyamide. Direct treatment with methanesulfonyl chloride forms oxazolines in good yields.

Synthesis of novel aromatic macrolactones via ring closing metathesis of substituted phenylalkanoic acid allylic esters

(Chemical Equation Presented) Stable aromatic macrolactones have been synthesized and characterized from 2- and 3-substituted phenylalkanoic acid systems in modest yields.