833-20-5Relevant academic research and scientific papers
Microwave-mediated Newman-Kwart rearrangement in water
Hoffmann, Ina,Schatz, Jürgen
, p. 80692 - 80699 (2016/09/09)
For the first time the unimolecular Newman-Kwart rearrangement is performed in pure water. The elevated temperatures required for the 1,3-aryl shift are easily accomplished by microwave irradiation. Differently functionalized substrates underline the expe
A comparison of commercial microwave reactors for scale-up within process chemistry
Moseley, Jonathan D.,Lenden, Philip,Lockwood, Mark,Ruda, Katinka,Sherlock, Jon-Paul,Thomson, Anthony D.,Gilday, John P.
, p. 30 - 40 (2012/12/31)
Seven commercially available microwave reactors designed for limited scale-up have been investigated using a highly reliable and robust reaction (the Newman-Kwart rearrangement). The use of a single reaction has enabled the comparison to be made across the range of different reactor types and scales. Overall, all reactors gave reliable scale-up from small scale, and performance equivalent to one another on large scale. A more detailed comparison between them is given in the concluding section.
The Newman-Kwart rearrangement: A microwave kinetic study
Gilday, John P.,Lenden, Philip,Moseley, Jonathan D.,Cox, Brian G.
, p. 3130 - 3134 (2008/09/19)
(Chemical Equation Presented) The kinetic profile of the Newman-Kwart rearrangement has been evaluated using microwave heating. After first demonstrating equivalence between conventional convective heating and microwave heating, data was gathered and anal
The Newman-Kwart rearrangement re-evaluated by microwave synthesis
Moseley, Jonathan D.,Sankey, Rosalind F.,Tang, Olivier N.,Gilday, John P.
, p. 4685 - 4689 (2007/10/03)
The Newman-Kwart rearrangement (NKR) has been re-evaluated by microwave heating. Microwave technology has proven to be ideal for investigating this high temperature rearrangement and facilitated the confirmation of many aspects of this valuable reaction.
