83300-58-7Relevant academic research and scientific papers
SYNTHESIS OF DIPHENYLTHIOACETALS OF POLYCONJUGATED KETENES FROM GEM-DI(PHENYLTHIO)CYCLOPROPYL KETONES
Il'ina, N. A.,Kulinkovich, O. G.
, p. 1272 - 1275 (2007/10/02)
The condensation of methyl gem-di(phenylthio)cyclopropyl ketones and substituted benzaldehydes gave a series of 1-(3-arylpropenoyl)-2,2-di(phenylthio)cyclopropanes.The reduction of these cyclopropanes with sodium borohydride and subsequent dehydration of
A Novel One-Flask Cyclopropanation and Vinylcyclopropanation Method for α-Enones. Copper(I)-Induced γ-Thiophenoxide Removal from Conjugate Adducts
Cohen, Theodore,Myers, Michael
, p. 457 - 460 (2007/10/02)
A novel concept for performing a one-flak cyclopropanation of conjugated enones consists of conjugate addition of an appropriate phenylthio-stabilized organolithium compound followed by treatment of the resulting enolate anion with cuprous trifluoromethan
SYNTHESIS AND ISOMERIZATION OF 1-ACYL-2,2-DI(PHENYLTHIO)CYCLOPROPANES
Kulinkovich, O. G.,Tishchenko, I. G.,Reznikov, I. V.,Roslik, N. A.
, p. 1446 - 1450 (2007/10/02)
The reaction of 1-acyl-2,2-dichlorocyclopropanes with sodium thiophenolate in methanol leads to the products from nucleophilic substitution of the chlorine atoms with retention of the cyclopropane ring.The obtained 1-acyl-2,2-di(phenylthio)cyclopropanes i
