83333-89-5Relevant academic research and scientific papers
Adaptation of the photo-induced [1,3]-allylic phenylthio shift to the preparation of functionalized diquinanes
Usui, Shuji,Paquette, Leo A.
, p. 3495 - 3498 (2007/10/03)
The feasibility of utilizing the little known photo-induced [1,3]- allylic phenylthio shift in the context of functionalized diquinane construction has been tested.
SYNTHESE NEUER ORGANOELEMENTSUBSTITUIERTER PENTADIENE (1)
Kauffmann, Thomas,Gaydoul, Klaus-Ruediger
, p. 4067 - 4070 (2007/10/02)
By applying four different methods twelve new organoelement substituted pentadienes have been prepared.They contain one or two organoelement groups. - Pentadienyllithium (2) reacted with Cl-SPh, Br-SePh, Cl-PPh2, and Cl-AsPh2 (lone pair at the element) ex
TOTAL SYNTHESIS OF 5-DESOXYLEUKOTRIENE D. A NEW AND USEFUL EQUIVALENT OF THE 4-FORMYL-TRANS,TRANS-1,3-BUTADIENYL ANION
Corey, E. J.,Hoover, Dennis J.
, p. 3463 - 3466 (2007/10/02)
The first total synthesis of 5-desoxyleukotriene D (14) is reported.The route of synthesis utilizes a novel method for five-carbon chain extension.The availability of 14 allowed experimental demonstration that the 5-hydroxyl function is important for biological activity of the slow reacting substances.
