83396-72-9

Basic information

• Product Name: 2-(benzoylamino)-3-(2-thienyl)acrylic acid
• Synonyms: 2-(benzoylamino)-3-(2-thienyl)acrylic acid
• CAS NO: 83396-72-9
• Molecular Formula: C₁₄H₁₁NO₃S
• Molecular Weight: 273.30704
• Mol File: 83396-72-9.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(benzoylamino)-3-(2-thienyl)acrylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(benzoylamino)-3-(2-thienyl)acrylic acid(83396-72-9)
• EPA Substance Registry System: 2-(benzoylamino)-3-(2-thienyl)acrylic acid(83396-72-9)

Safety Data

• Hazardous Substances Data: 83396-72-9(Hazardous Substances Data)

Upstream product

• 495-69-2 Hippuric Acid 
• 98-03-3 thiophene-2-carbaldehyde 
• 68100-05-0 (Z)-2-phenyl-4-(thiophen-2-ylmethylene)oxazol-5(4H)-one 

Relevant articles and documents

UNUSUAL AMINO ACIDS. IV. ASYMMETRIC SYNTHESIS OF THIENYLALANINES

(Z)-2-N-Acylamino-3-thienyl-acrylic acids and thei esters were prepared by known procedures and hydrogenated to the corresponding optically active 2-N-acetyl(or benzoyl)-3-(2- or 3-thienyl)-alanines with optically yields up to 90percent using the rhodium complexes of 'PROPRAPHOS" 6a,b and O,N-bis(diphenylphosphino)-2-exo-hydroxy,3-endo-methylamino-norbornane 6c as chiral catalysts.Recrystallization and deacylation of the obtained amino acid derivatives yields the optically pure hydrochlorides of the thienylalanines as the free amino acids.