83403-41-2Relevant academic research and scientific papers
Palladium catalyzed synthesis of mandelate derivatives from arylboronic acids and glyoxylate hemiacetals
Sugaya, Mariko,Yamamoto, Tetsuya,Shinozaki, Hiraku
supporting information, p. 2495 - 2497 (2017/05/31)
NHC-coordinated cyclometalated palladium(II) catalyzed addition of arylboronic acids to methyl 2-hydroxy-2-methoxyacetate gave corresponding various functionalized methyl mandelate derivatives in good yields.
Generation of iminyl copper species from α-azido carbonyl compounds and their catalytic C-C bond cleavage under an oxygen atmosphere
Chiba, Shunsuke,Zhang, Line,Ang, Gim Yean,Hui, Benjamin Wei-Qiang
supporting information; experimental part, p. 2052 - 2055 (2010/07/04)
Figure presented A copper-catalyzed reaction of α-azidocarbonyl compounds under an oxygen atmosphere is reported where nitriles are formed via C-C bond cleavage of a transient iminyl copper intermediate. The transformation is carried out by a sequence of denitrogenative formation of iminyl copper species from α-azidocarbonyl compounds and their C-C bond cleavage, where molecular oxygen (1 atm) is a prerequisite to achieve the catalytic process and one of the oxygen atoms of O2 was found to be incorporated into the β-carbon fragment as a carboxylic acid.
