83462-16-2

Basic information

• Product Name: 2-acetoxymenthone
• CAS NO: 83462-16-2
• Molecular Weight: 212.289
• Mol File: 83462-16-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-acetoxymenthone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetoxymenthone(83462-16-2)
• EPA Substance Registry System: 2-acetoxymenthone(83462-16-2)

Safety Data

• Hazardous Substances Data: 83462-16-2(Hazardous Substances Data)

Upstream product

• 72311-09-2 5-methyl-1-<(trimethylsilyl)oxy>-6-isopropylcyclohexene 
• 546-67-8 lead(IV) tetraacetate 
• 10458-14-7 (2R,5S)-menthone 
• 1600-27-7 mercury(II) diacetate 

Relevant articles and documents

REACTIVITY OF ORGANOTIN COMPOUNDS. XXIII. REACTION OF LEAD TETRAACETATE WITH TRIETHYLSTANNYL AND TRIMETHYLSILYL ETHERS OF THE ENOLS OF CYCLIC KETONES AS A METHOD FOR THE PRODUCTION OF 2-ACETOXY KETONES

The reactions of 1-cyclohexenyloxytriethyltin with lead tetraacetate and (diacetoxyiodo)benzene and the reaction of the trimethylsilyl ethers of the enols of cyclopentanone, cyclohexanone, 2-methylcyclohexanone (2-methyl-1-cyclohexenyloxytrimethylsilane and 6-methyl-1-cyclohexenyloxytrimethylsilane), cholestan-3-one, dl-camphor, and 1-methone with lead tetraacetate at room temperature in methylene chloride were investigated.The reaction of 1-cyclohexenyloxytriethyltin with lead tetraacetate and (diacetoxyiodo)benzene leads to the formation of 2-acetoxycyclohexanone and 2,2'-dioxo-1,1'-bicyclohexyl. 1-Cyclohexenyloxytrimethylsilane reacts with lead tetraacetate, giving (1,2-diacetoxycyclohexyloxy)trimethylsilane and (2-acetoxy-1-cyclo-hexenyloxy)trimethylsilane.As a result of the reactions of the trimethylsilyl ethers of the ketone enols with lead tetraacetate after treatment with BF3Et2O the corresponding 2-acetoxy ketones are obtained.The reaction mechanisms are discussed.