72311-09-2

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 10458-14-7 Menthone 

Downstream Products

• 79194-88-0 N-(3-Isopropyl-6-methyl-2-oxo-cyclohexylmethyl)-N-methyl-acetamide 
• 83462-16-2 2-acetoxymenthone 
• 301-04-2 lead acetate 
• 105367-46-2 ((3S,6S)-6-Isopropyl-3-methyl-cyclohex-1-enyloxy)-trimethyl-silane 
• 74185-00-5 (3R,6S)-3-methyl-6-(prop-2-yl)-1-trimethylsilyloxy-cyclohexene 
• 89-80-5 p-menthan-2-one 
• 105252-07-1 r-2,t-3-Dimethyl-c-6-(1-methylethyl)-1-cyclohexanon 
• 105252-08-2 r-2,c-3-Dimethyl-c-6-(1-methylethyl)-1-cyclohexanon 
• 946524-55-6 t-3-Methyl-c-6-(1-methylethyl)-r-2-(2-propenyl)-1-cyclohexanon 
• 105252-10-6 c-3-Methyl-c-6-(1-methylethyl)-r-2-(2-propenyl)-1-cyclohexanon 
• 59781-56-5 1--1-ethanon 
• 68298-49-7 (3-Methyl-6-(1-methylethyl)-1-cyclohexen-1-yl)acetat 
• 59781-47-4 r-2-Acetyl-t-3-methyl-c-6-(1-methylethyl)-1-cyclohexanon 

Relevant academic research and scientific papers

Preparation of a New, Highly Reactive Form of Iron(0) and Its Use in Deprotonation of Carbonyl Compounds

A new, highly reactive form of zerovalent iron, prepared from the reaction of methylmagnesium bromide and ferric chloride, has been found to deprotonate cyclic unsymmetrical ketones in the presence of trimethylsilyl chloride to give thermodynamic (more substituted) silyl enol ethers regiospecifically.

REGIOSPECIFIC PREPARATION OF THERMODYNAMIC SILYL ENOL ETHERS USING BROMOMAGNESIUM DIALKYLAMIDES

Thermodynamic silyl enol ethers are regiospecifically generated in high yield from cyclic ketones, bromomagnesium diisopropylamide (BMDA) and trimethylsilyl chloride.

NEW SYNTHESES OF α-N-ALKYLACETAMIDOMETHYLATED CARBONYL COMPOUNDS

Reaction of silyl enol ethers of ketones and aldehydes with 1,3,5-trialkylhexahydro-1,3,5-triazines in the presence of acetyl chloride and titanium tetrachloride afforded α-N-alkylacetamidomethylated carbonyl compounds.Thus, the reaction provides a convenient, general method for introduction of the N-alkylacetamidomethyl moiety at a position α to a carbonyl group.Keywords: N-alkylamidomethylation; 1,3,5-trialkylhexahydro-1,3,5-triazine; acetyl chloride; titanium tetrachloride; silyl enol ether