834917-63-4Relevant academic research and scientific papers
Polysulfonate supported chiral diamine-nickel catalysts: Synthesis and applications
Zhou, Jing-xuan,Zhu, Dong-yu,Chen, Jie,Zhang, Xue-jing,Yan, Ming,Chan, Albert S.C.
supporting information, (2021/01/25)
A series of chiral polysulfonate cyclohexyldiamine-Ni(II) catalysts were prepared via sulfur (VI) fluoride exchange click-reactions. The catalysts exhibited good catalytic activity and enantioselectivity in the Michael addition of malonates to nitroalkene
Enantio- and diastereoselective michael reaction of 1,3-dicarbonyl compounds to nitroolefins catalyzed by a bifunctional thiourea
Okino, Tomotaka,Hoashi, Yasutaka,Furukawa, Tomihiro,Xu, Xuenong,Takemoto, Yoshiji
, p. 119 - 125 (2007/10/03)
We synthesized a new class of bifunctional catalysts bearing a thiourea moiety and an amino group on a chiral scaffold. Among them, thiourea 1e bearing 3,5-bis(trifluoromethyl)benzene and dimethylamino groups was revealed to be highly efficient for the as
