83497-33-0

Basic information

• Product Name: methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside
• Synonyms: methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside
• CAS NO: 83497-33-0
• Molecular Weight: 345.19
• Mol File: 83497-33-0.mol

Chemical Properties

• CAS DataBase Reference: methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside(83497-33-0)
• EPA Substance Registry System: methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside(83497-33-0)

Safety Data

• Hazardous Substances Data: 83497-33-0(Hazardous Substances Data)

Upstream product

• 16718-95-9 methyl 4,6-O-benzylidene-2-deoxy-α-D-altropyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 100-52-7 benzaldehyde 
• 63598-31-2 methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose 
• 6752-48-3 methyl 2-deoxy-4,6-O-benzylidene-α-D-ribo-hexopyranoside 

Downstream Products

• 83497-34-1 methyl 3-O-benzoyl-6-bromo-2,6-dideoxy-4-O-methyl-α-D-ribo-hexopyranoside 
• 4092-45-9 methyl 2,6-dideoxy-α-D-ribo-hexopyranoside 
• 75044-07-4 methyl 4-O-benzoyl-3-benzoylamino-2,3,6-trideoxy-3-C-methyl-α-L-xylo-hexopyranoside 
• 172603-41-7 methyl 4-O-benzyl-2,6-dideoxy-β-L-lyxo-hexopyranoside 
• 94062-88-1 (3S,4S,5S,7S)-4-Benzyloxy-7-methoxy-5-methyl-6-oxa-1-aza-spiro[2.5]octane 
• 93978-85-9 methyl 4-O-benzyl-2,6-dideoxy-β-L-threo-hexopyranosid-3-ulose 
• 93960-56-6 methyl 3-O-benzoyl-2,6-dideoxy-β-L-lyxo-hexopyranoside 
• 93960-59-9 methyl 4-O-benzoyl-2,6-dideoxy-β-L-lyxo-hexopyranoside 
• 93978-83-7 methyl 4-O-benzyl-2,6-dideoxy-β-L-threo-hexopyranosid-3-ulose 
• 93978-82-6 methyl 3-O-benzoyl-4-O-benzyl-2,6-dideoxy-β-L-lyxo-hexopyranoside 
• 93978-91-7 N-((2S,3S,4R,6S)-3-Benzyloxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-benzamide 
• 93978-78-0 methyl 3-O-benzoyl-2,6-dideoxy-4-O-(2-methoxyethoxymethyl)-β-L-lyxo-hexopyranoside 
• 93978-90-6 methyl 3-benzoylamino-2,3,6-trideoxy-4-O-(2-methoxyethoxymethyl)-3-C-methyl-β-L-xylo-hexopyranoside 
• 123077-06-5 methyl 4-O-benzoyl-2,3,6-trideoxy-3-<2-(p-tolylsulfonyl)hydrazino>-α-D-ribo-hexopyranoside 

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BRANCHED-CHAIN SUGARS. XXXV. THE SYNTHESIS OF L-RUBRANITROSE (2,3,6-TRIDEOXY-3-C-METHYL-4-O-METHYL-3-NITRO-L-XYLO-HEXOPYRANOSE).

The compound was stereoselectively synthesized from methyl 2,6-dideoxy-4-O-methyl- beta -L-threo-hexopyranosid-3-ulose through the successive conversions; cyanomesylation, reductive spiro aziridine formation, reductive ring-opening to the methyl-branched amino sugar, oxidation to the corresponding nitro sugar.