75044-07-4

Upstream product

• 81703-35-7 N-[(R)-1-((1S,2S)-1,2-Dihydroxy-propyl)-1-methyl-but-3-enyl]-benzamide 
• 98-88-4 benzoyl chloride 
• 109978-72-5 ((2S,3S,6R)-3-Hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl)-carbamic acid tert-butyl ester 
• 67-56-1 methanol 
• 109978-67-8 Methyl-3-<(tert-butoxycarbonyl)amino>-2,3,6-tridesoxy-3-C-methyl-α-L-erythro-hexopyranosid-4-ulose 
• 109978-67-8 ((2S,6R)-6-Methoxy-2,4-dimethyl-3-oxo-tetrahydro-pyran-4-yl)-carbamic acid tert-butyl ester 
• 109978-72-5 Methyl-3-<(tert-butoxycarbonyl)amino>-2,3,6-tridesoxy-3-C-methyl-α-L-xylo-hexopyranosid 
• 93978-88-2 Methanesulfonic acid (2S,3R,4R,6S)-3-benzyloxy-4-cyano-6-methoxy-2-methyl-tetrahydro-pyran-4-yl ester 
• 93960-55-5 methyl 3-O-benzoyl-4-O-benzyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside 
• 93960-56-6 methyl 3-O-benzoyl-2,6-dideoxy-β-L-lyxo-hexopyranoside 
• 93978-85-9 methyl 4-O-benzyl-2,6-dideoxy-β-L-threo-hexopyranosid-3-ulose 
• 94062-88-1 (3S,4S,5S,7S)-4-Benzyloxy-7-methoxy-5-methyl-6-oxa-1-aza-spiro[2.5]octane 
• 172603-41-7 methyl 4-O-benzyl-2,6-dideoxy-β-L-lyxo-hexopyranoside 
• 83497-33-0 methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-α-D-ribo-hexopyranoside 

Downstream Products

• 74966-76-0 methyl 3-benzamido-2,3,6-trideoxy-3-C-methyl-α-L-xylo-hexopyranoside 

Relevant academic research and scientific papers

Enolates of Carbohydrates, 6. - New Syntheses of Derivatives of 3-Amino-2,3,6-trideoxy-3-C-methyl-L-xylo-hexopyranose, L-Vancosamine, D-Rubranitrose, and Precursors of L-Decilonitrose and D-Kijanose

3-C-Methylated products D-and L-12a,b with erythro- and D- and L-13a,b with threo-configuration are obtained by stereoselective α-C-alkylation of 3-amino-2,3,6-trideoxy-4-uloses D- and L-10a,b.Reduction at low temperatures with L-selectride generates the

Branched-chain sugars. XXXVI. A new synthesis of methyl 4-O-benzoyl-3-benzoylamino-2,3,6-trideoxy-3-C-methyl-α-L-xylo-hexopyranoside, a derivative of the branched-chain amino sugar of antibiotic A35512B

The compound was synthesized from methyl 4-0-benzyl-2,6-dideoxy- beta -L-threo-hexopyranosid-3-ulose through cyanomesylation, reductive spiro aziridine formation, and reductive ring-opening. When (2-methyoxyethoxymethyl) group was used as the protecting g

SYNTHESIS OF THE N-BENZOYL DERIVATIVES OF L-ARABINO,L-XYLO AND L-LYXO (L-VANCOSAMINE) ISOMERS OF 2,3,6-TRIDEOXY-3-C-METHYL-3-AMINOHEXOSE FROM A NON-CARBOHYDRATE PRECURSOR

The synthesis of the N-benzoyl derivatives of L-arabino (10),L-xylo (13) and L-lyxo (L-vancosamine) (12) 2,3,6-trideoxy-3-C-methyl-3-aminohexose from the (2S,3R) diol (1) prepared in fermenting bakers' yeast from α-methylcinnamaldehyde and acetaldehyde is reported.

Isolation and Structure of the Novel Branched-Chain Amino Sugar Derived from Antibiotic A35512B

Methanolysis of glycopeptide antibiotic A35512B with 1.5 N HCl (methanol) gave a new 2,3,6-trideoxy amino sugar.The structure of this amino sugar was determined by NMR and CD techniques and shown to be 3-amino-2,3,6-trideoxy-3-C-methyl-L-xylo-hexopyranose