83500-87-2Relevant academic research and scientific papers
The synthesis, characterization and comparative anticorrosion study of some organotin(IV) 4-chlorobenzoates
Kurniasih, Hastin,Nurissalam, Muhamad,Iswantoro, Bambang,Afriyani, Hapin,Qudus, Hardoko Insan,Hadi, Sutopo
, p. 2377 - 2383 (2016/02/27)
The synthesis of 3 compounds of a series of dibutyl(IV) di-4-chlorobenzoate, diphenyl(IV) di-4-chlorobenzoate and triphenyltin(IV) 4-chlorobenzoate have successfully been performed by reacting the dibutyltin(IV) dichloride, diphenyltin(IV) dichloride and triphenyltin(IV) chloride respectively via the dibutyltin(IV) oxide, diphenyltin(IV) dihydroxide and triphenyltin(IV) hydroxide with 4-chlorobenzoic acid. All compounds synthesized were well characterized by 1H and 13C NMR, IR and UV-Vis spectroscopies as well as based on the microanalytical data. The anticorrosion activity of these compounds were tested on Hot Roller Plate (HRP) mild steel in DMSO-HCl solution using potentiodynamic method. The results revealed that the triphenyltin(IV) 4-chlorobenzoate clearly showed the strongest inhibitor activity compared to the other derivatives, while diphenyltin(IV) compounds were better than that of dibutyltin(IV) analogous. The results reported here indicated that the optimal activity were depended on the ligand attached to the metal centre and might also be related to the number of carbon atoms present in the organotin(IV) used.
Solventless Reactions for the Synthesis of Organotin Clusters and Cages
Chandrasekhar, Vadapalli,Baskar, Viswanathan,Boomishankar, Ramamoorthy,Gopal, Kandasamy,Zacchini, Stefano,Bickley, Jamie F.,Steiner, Alexander
, p. 3710 - 3716 (2008/10/08)
Organotin clusters and cages have been synthesized in quantitative yields by using a benign solventless synthetic methodology. Using this method a variety of structural forms, which include the drum, O-capped cluster, tetranuclear oxo cage, discrete, and polymeric compounds, have been synthesized. All these compounds (1-11) have been characterized by spectroscopic and analytical techniques. The new compounds, which include the hexameric drum [n-BuSn(O)OCOAd]6 (Ad = adamantyl) 9, a triorganotin-based discrete structure Ph3SnO2C-C6-H 22,4,6-Me3 (10), and a polymer Ph3SnOSO 2-C6H3-2,5-Me2 (11), have been characterized by single-crystal X-ray crystallography.
Organotin Biocides. Part 11. Triphenyltin Benzoates: Electronic versus Steric Control of Structure
Molloy, Kieran C.,Blunden, Stephen J.,Hill, Robin
, p. 1259 - 1266 (2007/10/02)
Twenty four triphenyltin derivatives of substituted benzoic acids have been synthesised.On the basis of i.r., (119)Sn n.m.r. and Moessbauer spectroscopic data, structures have been assigned to these compounds as either tetrahedral monomers or trans-SnR3O2
13C AND 119Sn NMR STUDY OF SOME TRIPHENYLTIN(IV) CARBOXYLATES
Holecek, J.,Handlir, K.,Nadvornik, M.,Lycka, A.
, p. 147 - 154 (2007/10/02)
The 13C and 119Sn NMR spectra of CDCl3 solutions of aliphatic and aromatic triphenyltin(IV) carboxylates of the type Ph3SnOCOR (Ph = phenyl; R=H, CH3, C2H5, C(CH3)3, CF3, CH2Cl, CHCl2, CCl3, CH2Br and CHBr2) and of the type Ph3SnOCOC6H4X (X = H, 4-NH2, 4-
