83503-38-2Relevant academic research and scientific papers
Method for manufacturing acryloxypropysilane
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, (2008/06/13)
A method to manufacture acryloxypropylsilane to a high degree of purity is achieved by hydrosilation of (A) allyl acrylate or allyl methacrylate by (B) a hydrosilane compound, using (C) a platinum-containing compound as the catalyst and (D) an organic phosphorus compound as the promoter. The acryloxypropylsilane product is expressed by General Formula I where R1 represents a hydrogen or methyl group, R2 represents a hydrolyzable group, R3 represents an aryl, alkenyl or aryl group of carbon number 1-12, and n is 0, 1, 2, or 3.
SYNTHESIS OF ORGANOSILICON DERIVATIVES OF ACRYLIC ACIDS
Efimov, Yu. T.,Tandura, T. A.,Kopylov, V. M.,Androsenko, S. I.,Shkol'nik, M. I.
, p. 2083 - 2091 (2007/10/02)
A study of the reactions of organohydrochlorosilanes with allyl acrylate showed that the addition proceeds at the β-position in all cases.The acrylate-containing chlorosilanes react with acetic anhydride to give quantitative yield of the acetoxy derivatives.Study of the hydrolysis of the chloro and acetoxy derivatives showed the feasibility of the direct synthesis of the corresponding silanols.The reactivity of these compounds was studied.
