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999-55-3 Usage

Chemical Properties

colourless liquid


Allyl acrylate is a monofunctional monomer which function as a chain stopper.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

The unsaturated aliphatic hydrocarbons, like ALLYL ACRYLATE, are generally much more reactive than the alkanes, which are saturated aliphatic hydrocarbons. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. In the presence of various catalysts (such as acids) or initiators, compounds in this class can undergo very exothermic addition polymerization reactions. Many of these compounds undergo autoxidation upon exposure to the air to form explosive peroxides. These peroxide and polyperoxide substances are usually extremely unstable and liable to detonation. The peroxidation of butadiene has been involved in several serious industrial accidents. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Fire Hazard

ALLYL ACRYLATE is flammable.

Check Digit Verification of cas no

The CAS Registry Mumber 999-55-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,9 and 9 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 999-55:
123 % 10 = 3
So 999-55-3 is a valid CAS Registry Number.

999-55-3 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (44463)  Allyl acrylate, 95%, stab. with 4-methoxyphenol   

  • 999-55-3

  • 25g

  • 1559.0CNY

  • Detail
  • Alfa Aesar

  • (44463)  Allyl acrylate, 95%, stab. with 4-methoxyphenol   

  • 999-55-3

  • 100g

  • 4739.0CNY

  • Detail
  • Alfa Aesar

  • (L10138)  Allyl acrylate, tech. 90%, stab. with ca 100ppm 4-methoxyphenol   

  • 999-55-3

  • 5g

  • 443.0CNY

  • Detail
  • Alfa Aesar

  • (L10138)  Allyl acrylate, tech. 90%, stab. with ca 100ppm 4-methoxyphenol   

  • 999-55-3

  • 25g

  • 1714.0CNY

  • Detail



According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017


1.1 GHS Product identifier

Product name Allyl Acrylate

1.2 Other means of identification

Product number -
Other names 2-Propenoic acid, 2-propenyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:999-55-3 SDS

999-55-3Relevant articles and documents



Paragraph 0040-0041; 0043-0044; 0046-0047; 0049-0050; 0052, (2018/10/11)

A process for forming allyl acrylate, comprising contacting allyl ether in solution with a solvent with one or more oxidants in the presence of a mesoporous manganese oxide (MnOx) catalyst.

Synthesis of unsaturated esters via highly efficient esterification catalyzed by polymer grafted quarternary ammonium salts as triphase catalysts

Liang, Zheng Yong,Wang, Li Li,Liu, Hui,Huang, Jin Shuo

, p. 1558 - 1561 (2013/09/12)

A series of unsaturated esters were prepared via condensation of sodium carboxylates and alkenyl halide under the condition of macroporous polystyrene grafted quarternary ammonium salt as recyclable phase transfer catalyst, NaI as co-catalyst, Cu powder as inhibitor and H2O as solvent. Under optimal conditions, products yields are 78.2~ 96.0%. The catalyst can be convenient recycled and reutilized for about five times without losing its activity obviously.

A modular rearrangement approach toward medicinally relevant phosphinic structures

Rogakos, Vassilis,Georgiadis, Dimitris,Dive, Vincent,Yiotakis, Athanaslos

supporting information; experimental part, p. 4696 - 4699 (2009/12/08)

An unprecedented coupling of a P - C and a C - C bond-forming event In a practical operation was developed to access medicinally relevant phosphinic structures. The strategy relies on an Ireland-Claisen rearrangement triggered by the phospha-Michael addition of silyl phosphonltes to allyl acrylates. This protocol was extended to a more versatile three-component variant that utilizes phosphinic acids, acryloyl chlorides, and allylic alcohols as starting materials.

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