83505-24-2

Basic information

• Product Name: 2-Fluoro-3,3,3-trimethoxy-1-(2-methoxy-phenyl)-propan-1-one
• Synonyms: 2-Fluoro-3,3,3-trimethoxy-1-(2-methoxy-phenyl)-propan-1-one
• CAS NO: 83505-24-2
• Molecular Weight: 272.273
• Mol File: 83505-24-2.mol

Chemical Properties

• CAS DataBase Reference: 2-Fluoro-3,3,3-trimethoxy-1-(2-methoxy-phenyl)-propan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Fluoro-3,3,3-trimethoxy-1-(2-methoxy-phenyl)-propan-1-one(83505-24-2)
• EPA Substance Registry System: 2-Fluoro-3,3,3-trimethoxy-1-(2-methoxy-phenyl)-propan-1-one(83505-24-2)

Safety Data

• Hazardous Substances Data: 83505-24-2(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 83505-21-9 o-methoxy-2,3,3,3-tetrafluoropropiophenone 

Relevant articles and documents

SYNTHESIS AND INTRAMOLECULAR CYCLISATION OF ortho-HYDROXY-2,3,3,3-TETRAFLUOROPROPIOPHENONE. FORMATION OF 3-FLUORO-4-HYDROXYCOUMARIN

Acidic hydrolysis of 1-(o-methoxyphenyl)pentafluoropropene 1 gave o-hydroxy-2,3,3,3-tetrafluoropropiophenone 2 and o-methoxy-2,3,3,3-tetrafluoropropiophenone 3.Compound 2 when treated with aqueous potassium hydroxide or methanolic sodium methoxide gave 3-fluoro-4-hydroxycoumarin 4.Structure of 4 has been established by spectral means and some chemical reactions.The cyclisation mechanism of 2 is discussed.