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(2,2-Dimethyl-but-3-enylsulfanyl)-benzene is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

83577-62-2

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83577-62-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 83577-62-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,3,5,7 and 7 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 83577-62:
(7*8)+(6*3)+(5*5)+(4*7)+(3*7)+(2*6)+(1*2)=162
162 % 10 = 2
So 83577-62-2 is a valid CAS Registry Number.

83577-62-2Downstream Products

83577-62-2Relevant academic research and scientific papers

2,3-Sigmatropic rearrangement of sulfonium ylides generated by addition of samarium carbenoids

Kunishima, Munetaka,Nakata, Daisuke,Goto, Chikako,Hioki, Kazuhito,Tani, Shohei

, p. 1366 - 1368 (2007/10/03)

Allylic sulfides are transformed into homoallylic sulfides with complete allylic inversion by treatment with SmI2 and CH2I2 in THF. The reaction will involve allylic sulfonium ylides as an intermediate, which undergoes 2,3-rearrangement.

A METHOD FOR METHYLIDENATION AND ETHYLIDENATION OF AN ALLYLIC THIOETHER LEADING TO A 2,3-SIGMATROPIC REARRANGEMENT. FAILURE OF THE SIMMONS-SMITH REACTION IN THE PRESENCE OF THIOETHERS

Kosarych, Zenyk,Cohen, Theodore

, p. 3019 - 3022 (2007/10/02)

Allylic phenylthioethers are converted in one step to homoallylic phenylthioethers by treatment with methylene iodide or ethylidene iodide in the presence of diethylzinc but not zinc-copper or zinc-silver couples; furthermore, Simmons-Smith cyclopropanati

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