835873-06-8

Upstream product

• 57056-93-6 N-methyl-2-iodoaniline 
• 100-07-2 4-methoxy-benzoyl chloride 
• 329939-01-7 N-(2-iodophenyl)-4-methoxybenzamide 
• 74-88-4 methyl iodide 
• 90446-67-6 4-((tert-butyldimethylsilyl)oxy)benzoyl chloride 
• 835873-00-2 4-(tert-butyldimethylsilanyloxy)-N-(2-iodophenyl)-N-methylbenzamide 
• 835873-02-4 4-hydroxy-N-(2-iodophenyl)-N-methylbenzamide 

Relevant academic research and scientific papers

Aniline-Type Hypervalent Iodine(III) for Intramolecular Cyclization via C?H Bond Abstraction of Hydrocarbons Containing N- and O-Nucleophiles

We developed a method for the preparation of (diacetoxyiodo)-2-(N-alkylamido)benzene as an aniline-type hypervalent iodine(III). We also achieved direct cyclizations via C?H bond abstraction, such as the Hofmann-L?ffler-Freytag reaction, a direct amination, and a direct lactonization, using the aniline-type hypervalent iodine(III) to obtain corresponding products in high yields. (Figure presented.).

Radical cyclization approach to spirocyclohexadienones

(Chemical Equation Presented) Cyclization of an aryl radical at the ipso position of a p-O-aryl-substituted acetamide or benzamide generates oxindoles or quinolones bearing spirocyclohexadienone rings. This versatile reaction is applied to formal synthese