83769-29-3Relevant academic research and scientific papers
Synthesis of 3-fluoropyruvates from glycidic-α-cyanoesters
Chehidi,Chaabouni,Baklouti
, p. 237 - 241 (1996)
The decyanation of α-cyano-β-fluoro-α-hydroxyesters is achieved, at room temperature, by action of Ni(OAc)2. The corresponding 3-fluoropyruvates are obtained in good yields.
Methode generale d'obtention des α-ceto esters β-fluores
Ourari, Ali,Condom, Roger,Guedj, Roger
, p. 2707 - 2710 (2007/10/02)
A general method of synthesis of 3-alkyl (or aryl) 3-fluoro 2-oxo esters is described.The opening of glycidic esters with HF-pyridine (70percent w/w) followed by oxidation with Jones reagent, give the corresponding derivatives of fluoropyruvic esters in good yields.
