838846-30-3Relevant academic research and scientific papers
Greening the Wacker process
Kulkarni, Mukund G.,Shaikh, Yunnus B.,Borhade, Ajit S.,Chavhan, Sanjay W.,Dhondge, Attrimuni P.,Gaikwad, Dnyaneshwar D.,Desai, Mayur P.,Birhade, Deekshaputra R.,Dhatrak, Nagorao R.
supporting information, p. 2293 - 2295 (2013/06/26)
Wacker oxidation of various terminal olefins with Pd0/C- KBrO3, a nontoxic, environmentally benign, and easy to handle catalyst system, was achieved in high isolated yields. The described protocol offers an alternative to the traditional Wacker system which uses CuCl 2 as co-catalyst. The catalyst is reusable while maintaining high activity and selectivity.
Pd(0)/C catalyzed efficient Wacker oxidation of functionalized terminal olefins
Kulkarni, Mukund G.,Bagale, Sharanappa M.,Shinde, Mahadev P.,Gaikwad, Dnyaneshwar D.,Borhade, Ajit S.,Dhondge, Attrimuni P.,Chavhan, Sanjay W.,Shaikh, Yunnus B.,Ningdale, Vijay B.,Desai, Mayur P.,Birhade, Deekshaputra R.
experimental part, p. 2893 - 2894 (2009/09/06)
Wacker oxidation of terminal olefins was carried out at room temperature and atmospheric pressure by using Pd(0)/C in THF/H2O (9:1). Palladium(0)/C was proven to be highly efficient catalyst for the Wacker oxidation of terminal olefins to the corresponding methyl ketones. The catalyst was reusable while maintaining its activity and selectivity to a high degree.
An expedient protocol for cyclopentenone annulation
Kulkarni, Mukund G.,Davawala, Saryu I.,Doke, Aniruddha K.,Pendharkar, Dhananjay S.
, p. 2919 - 2926 (2007/10/03)
A convenient and general protocol for the cyclopentenone annulation process is described.
