77783-92-7

Upstream product

• 93-17-4 3,4-dimethoxyphenylacetonitrile 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 188476-12-2 4-((E)-2-Allyloxy-vinyl)-1,2-dimethoxy-benzene 
• 100603-78-9 (+/-)-α-allyl-3,4-dimethoxyphenylethanenitrile 

Downstream Products

• 838846-30-3 2-(3,4-dimethoxy-phenyl)-4-oxo-pentanal 
• 440361-91-1 [1-(3,4-dimethoxy-phenyl)-4-oxo-cyclohex-2-enyl]-acetaldehyde 
• 21104-34-7 N-methyl-3a-<3,4-(dimethoxy)phenyl>-2,3,3a,4,5,6,7,7a-octahydroindole-2,6-dione 
• 87014-19-5 (3aR,7aR)-3a-(3,4-Dimethoxy-phenyl)-hexahydro-benzofuran-2,6-dione 
• 6023-73-0 mesembrine 
• 440361-90-0 4-allyl-4-(3,4-dimethoxyphenyl)cyclohex-2-enone 
• 77783-94-9 (+/-)-4-allyl-4-(3,4-dimethoxyphenyl)-2-<2-(5,5-dimethyl-1,3-dioxan-2-yl)ethyl>cyclohex-2-en-1-one 

Relevant academic research and scientific papers

Allyl vinyl ethers via Wittig olefination: A short and efficient synthesis of (±)-mesembrine

A Wittig olefination-Claisen rearrangement approach has been successfully applied to a short and efficient synthesis of (±)-mesembrine.

An expedient protocol for cyclopentenone annulation

A convenient and general protocol for the cyclopentenone annulation process is described.

Applications of Substituted Arylacetaldehydes in the Total Synthesis of Mesembrane Alkaloids. Part 2. An Alternative Systhesis of (+/-)-Sceletium Alkaloid A4

The substituted arylacetaldehydes (+/-)-2-(3,4-dimethoxyphenyl)pent-4-enal (1c) is shown to serve as a precursor in the total synthesis of the mesembrane alkaloid (+/-)-sceletium alkaloid A4.