83897-71-6

Basic information

• Product Name: (Z)-1-Phenyl-1-tridecene
• Synonyms: (Z)-1-Phenyl-1-tridecene
• CAS NO: 83897-71-6
• Molecular Weight: 258.447
• Mol File: 83897-71-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (Z)-1-Phenyl-1-tridecene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-Phenyl-1-tridecene(83897-71-6)
• EPA Substance Registry System: (Z)-1-Phenyl-1-tridecene(83897-71-6)

Safety Data

• Hazardous Substances Data: 83897-71-6(Hazardous Substances Data)

Upstream product

• 645-66-9 lauric anhydride 
• 588-73-8 (Z)-β-bromostyrene 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 105-74-8 dilauryl peroxide 
• 536-74-3 phenylacetylene 
• 112-54-9 Dodecanal 
• 7016-55-9 benzyl-triethylphosphonium bromide 

Relevant articles and documents

Highly Stereoselective and General Synthesis of (E)-Stilbenes and Alkenes by Means of an Aqueous Wittig Reaction

The chemoselective formation of trialkyl(benzylidene) ylides in water and their Wittig reaction with aromatic and. aliphatic aldehydes provides a practical, stereoselective and environmentally benign route to valuable (E)-stilbenes and alkenes. The synthesis of the phytoalexin resveratrol is described, J.n addition, the method allows for a gram-scale synthesis of the anticancer agent DMU-212 utilizing no organic solvent at any stage. Wiley-VCH Verlag GmbH & Co. KGaA.

Hydroalkylation of terminal aryl alkynes with alkyl diacyl peroxides

A photo and nickel co-catalyzed hydroalkylation of terminal aryl alkynes enabled Z-preferred olefin synthesis has been developed under mild conditions. Alkyl diacyl peroxides were utilized as a new type of alkylation reagents and afforded Z-olefins as the major products in moderate to good yields.

Wittig Reagents Bound to Cross-Linked Polystyrenes

Insoluble benzyltriarylphosphonium and methyltriarylphosphonium salts have been prepared on 2percent and 8percent divinylbenzene cross-linked polystyrene and on 20percent divinylbenzene cross-linked macroporous polystyrene.Phosphoranes were generated with sodium methoxide or sodium ethoxide in THF and with the dimethylsulfinyl carbanion in Me2SO from the benzyl- and methylphosphonium salts, respectively.Reactions of the phosphoranes with a variety of aldehydes and ketones provided alkenes in 73-96percent yields (by GLC analysis) with the 2percent cross-linked polymer, 52-77percent yields with the 8percent cros s-linked polymer, and 72-87percent yields with the 20percent cross-linked macroporous polymer.The rates of phosphorane generation and alkene formation depend on the polymer, decreasing in the order 2percent > 20percent macroporous > 8percent cross-linked.The fraction of E double bond product from the benzylphosphonium salt and either benzaldehyde or cinnamaldehyde is greater with the 20percent cross-linked macroporous polymer than with the 2percent cross-linked polymer.The byproduct polymer-bound phosphine oxides were reduced to phosphines with trichlorsilane, and the phosphines were reused for Wittig synthesis.A quantitative 31P-NMR analysis of phosphine and phosphine oxide residues in polystyrene gels is reported.