84-85-5Relevant articles and documents
Synthesis of propanolamine side chain deuterated propanolol, propranolol-diol and 4-hydroxypropranolol
Walker,Nelson
, p. 905 - 912,907,910,911 (1978)
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Tuning the Reactivity of Peroxo Anhydrides for Aromatic C-H Bond Oxidation
Pilevar, Afsaneh,Hosseini, Abolfazl,?ekutor, Marina,Hausmann, Heike,Becker, Jonathan,Turke, Kevin,Schreiner, Peter R.
, p. 10070 - 10079 (2018/09/06)
Phenol moieties are key structural motifs in many areas of chemical research from polymers to pharmaceuticals. Herein, we report on the design and use of a structurally demanding cyclic peroxide (spiro[bicyclo[2.2.1]heptane-2,4′-[1,2]dioxolane]-3′,5′-dione, P4) for the direct hydroxylation of aromatic substrates. The new peroxide benefits from high thermal stability and can be synthesized from readily available starting materials. The aromatic C-H oxidation using P4 exhibits generally good yields (up to 96%) and appreciable regioselectivities.
Ambipolar transistor properties of 2,2′-binaphthosemiquinones
Higashino, Toshiki,Kumeta, Shohei,Tamura, Sumika,Ando, Yoshio,Ohmori, Ken,Suzuki, Keisuke,Mori, Takehiko
supporting information, p. 1588 - 1594 (2015/04/27)
Binaphthosemiquinones are proved to show ambipolar transistor properties. These compounds have characteristic blue colors owing to the small energy gaps, because the quinone part acts as an electron acceptor and the alkoxy group acts as an electron donor. Accordingly, these molecules have an analogous electronic structure to indigo. The crystal structure changes depending on the alkoxy groups, though these compounds generally have stacking structures.